(2R,3R,4R,5S)-3-[(2R,3R,4R,5S,6R)-3,4-Dihydroxy-6-hydroxymethyl-5-((2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-hydroxymethyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-2-yloxy]-6-(4-nitro-benzyloxyamino)-hexane-1,2,4,5-tetraol | 129114-74-5

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (2R,3R,4R,5S)-3-[(2R,3R,4R,5S,6R)-3,4-Dihydroxy-6-hydroxymethyl-5-((2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-hydroxymethyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-2-yloxy]-6-(4-nitro-benzyloxyamino)-hexane-1,2,4,5-tetraol
• 英文别名: (2R,3R,4R,5S)-3-[(2R,3R,4R,5S,6R)-3,4-dihydroxy-6-(hydroxymethyl)-5-[(2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]oxy-6-[(4-nitrophenyl)methoxyamino]hexane-1,2,4,5-tetrol
• CAS: 129114-74-5
• 化学式: C₂₅H₄₀N₂O₁₈
• 分子量: 656.595
• InChiKey: GTZAEXZCJKVJPH-NAGWMYPDSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -5.7
• 重原子数：
  45
• 可旋转键数：
  15
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.76
• 拓扑面积：
  327
• 氢给体数：
  12
• 氢受体数：
  19

反应信息

• 作为反应物：
  描述：

  (2R,3R,4R,5S)-3-[(2R,3R,4R,5S,6R)-3,4-Dihydroxy-6-hydroxymethyl-5-((2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-hydroxymethyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-2-yloxy]-6-(4-nitro-benzyloxyamino)-hexane-1,2,4,5-tetraol 生成 {(2S,3R,4R,5R)-4-[(2R,3R,4S,5R,6R)-3,4-Dimethoxy-6-methoxymethyl-5-((2R,3R,4S,5R,6R)-3,4,5-trimethoxy-6-methoxymethyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-2-yloxy]-2,3,5,6-tetramethoxy-hexyl}-trimethyl-ammonium
  参考文献：
  名称：

  1-Alkoxyamino-1-deoxy alditols, useful u.v.-absorbing derivatives of neutral and acidic oligosaccharides

  摘要：

  DOI：

  10.1016/0008-6215(90)84230-r
• 作为产物：
  描述：

  (2S,3R,4R,5R)-4-[(2R,3R,4R,5S,6R)-3,4-Dihydroxy-6-hydroxymethyl-5-((2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-hydroxymethyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-2-yloxy]-2,3,5,6-tetrahydroxy-hexanal O-(4-nitro-benzyl)-oxime 在 吡啶 、 盐酸 、 sodium cyanoborohydride 作用下， 生成 (2R,3R,4R,5S)-3-[(2R,3R,4R,5S,6R)-3,4-Dihydroxy-6-hydroxymethyl-5-((2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-hydroxymethyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-2-yloxy]-6-(4-nitro-benzyloxyamino)-hexane-1,2,4,5-tetraol
  参考文献：
  名称：

  1-Alkoxyamino-1-deoxy alditols, useful u.v.-absorbing derivatives of neutral and acidic oligosaccharides

  摘要：

  DOI：

  10.1016/0008-6215(90)84230-r

文献信息

• DEYN, WOLFGANG VON;YORK, WILLIAM S.;ALBERSHEIM, PETER;DARVILL, ALAN G., CARBOHYDR. RES., 201,(1990) N, C. 135-144
  作者：DEYN, WOLFGANG VON、YORK, WILLIAM S.、ALBERSHEIM, PETER、DARVILL, ALAN G.

  DOI：——

  日期：——