[(3aR,5S,6aR)-5-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl]-methanesulfonic acid isopropyl ester | 134222-11-0

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: [(3aR,5S,6aR)-5-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl]-methanesulfonic acid isopropyl ester
• CAS: 134222-11-0
• 化学式: C₁₆H₂₈O₈S
• 分子量: 380.46
• InChiKey: FHRNYYLNJWXGRP-ZLMOABSSSA-N

反应信息

• 作为产物：
  描述：

  [(3aR,5S,6aR)-5-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-dihydro-furo[2,3-d][1,3]dioxol-(6E)-ylidene]-methanesulfonic acid isopropyl ester 在 sodium tetrahydroborate 作用下， 以85%的产率得到[(3aR,5S,6aR)-5-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl]-methanesulfonic acid isopropyl ester
  参考文献：
  名称：

  Synthesis of nucleoside sulfonates and sulfones

  摘要：

  Sulfonate analogues of adenine, cytidine and guanine monophosphates have been synthesized for the first time. The synthesis of ribose 3-sulfonate, a synthesis of sulfonyl disaccharides and dinucleotides and an improved synthesis of a ribose 3-sulfone is also reported.

  DOI：

  10.1016/s0040-4039(00)79642-0