[bis(μ-3,5-diisopropylpyrazolato)(3,5-diisopropylpyrazole)bis(heptanoato)dizinc(II)] | 1192129-85-3

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: [bis(μ-3,5-diisopropylpyrazolato)(3,5-diisopropylpyrazole)bis(heptanoato)dizinc(II)]
• CAS: 1192129-85-3
• 化学式: C₅₀H₈₈N₈O₄Zn₂
• 分子量: 996.08
• InChiKey: LUAOGRMDFUCWLS-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  zinc perchlorate 、 sodium heptanoate 、 3,5-二异丙基吡唑 以 甲醇 为溶剂， 以56%的产率得到[bis(μ-3,5-diisopropylpyrazolato)(3,5-diisopropylpyrazole)bis(heptanoato)dizinc(II)]
  参考文献：
  名称：

  Synthesis, structural and luminescence studies of some zinc complexes having pyrazole and carboxylate ligands

  摘要：

  Some zinc (II) complexes having formula [Zn(Pz(iPr2)H)(mu-Pz(iPr2))(RCOO)](2) [(Pz(iPr2)H = 3,5-diisopropylpyrazole, RCOO = carboxylate ligands with R is CH3 for 1, CF3 for 2, CH3(CH2)(2) for 3, CH3(CH2)(4) for 4 and CH3(CH2)(5) for 5] were prepared and structurally characterized by different techniques including single crystal X-ray. The X-ray studies suggested that all these complexes are centrosymmetric dinuclear with tetrahedral geometry around each zinc center. The pyrazole ligand is coordinated in both terminal as well as a bridging fashion whereas the carboxylates behave as monodentate ligand. All the complexes show hydrogen bonding between hydrogen atom of pyrazole (N-H of terminal pyrazole) and nonbonded oxygen atom of carboxylate. Out of these complexes only 5 [Zn(Pz(iPr2)H)(mu-Pz(iPr2))(CH3(CH2)(5)COO)](2) exhibited emission at room temperature. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2009.06.018