Amalogenin A acetate | 142878-26-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 内酯类
• 英文名称: Amalogenin A acetate
• CAS: 142878-26-0
• 化学式: C₂₃H₃₀O₆
• 分子量: 402.488
• InChiKey: DLTXVEJGJPLUTN-GLYORJKZSA-N

反应信息

• 作为产物：
  描述：

  Amaloside A 在 吡啶 、 硫酸 作用下， 反应 0.5h， 生成 Amalogenin A acetate
  参考文献：
  名称：

  Steroidal constituents from Amalocalyx yunnanesis

  摘要：

  Three steroidal constituents having the rare cis-B/C ring junctions (8-alpha-OH, 9-alpha-H), named amalogenin A, amaloside A and amaloside B, were isolated from the vine of Amalocalyx yunnanesis. The structures were deduced by precise NMR studies and confirmed by X-ray diffraction for amaloside A. The structures were shown to be 3-beta,8-alpha-dihydroxy-8-alpha,9-alpha,14-beta,17-beta,20(R)-pregn-5-ene-14,20-epoxy-13-carboxylic-20-lactone (amalogenin A) amalogenin A 3-O-beta-D-diginopyranoside (amaloside A) and amalogenin A 3-O-beta-D-glucopyranosyl(1-4)-beta-D-diginopyranoside (amaloside B).

  DOI：

  10.1016/0031-9422(92)80370-t