Ethanol, 1-[(2,4,5,6,7,7a-hexahydro-4,7-methano-1H-inden-4-yl)oxy]- | 1823917-46-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: Ethanol, 1-[(2,4,5,6,7,7a-hexahydro-4,7-methano-1H-inden-4-yl)oxy]-
• 英文别名: 1-(1-tricyclo[5.2.1.02,6]dec-2-enyloxy)ethanol
• CAS: 1823917-46-9
• 化学式: C₁₂H₁₈O₂
• 分子量: 194.27
• InChiKey: JSCLMOWEWUTCGC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.5
• 重原子数：
  14
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  29.5
• 氢给体数：
  1
• 氢受体数：
  2

文献信息

• (METH)ACRYLATE MANUFACTURING METHOD
  申请人：TOAGOSEI CO., LTD

  公开号：US20180118658A1

  公开（公告）日：2018-05-03

  The present invention provides a (meth)acrylate manufacturing method characterized in that when manufacturing a (meth) acrylate by an ester exchange reaction between an alcohol and a monofunctional (meth)acrylate using catalyst A and catalyst B together, contact treatment of the ester exchange reaction product with adsorbent C is performed. Catalyst A: One or more kinds of compounds selected from a group consisting of cyclic tertiary amines with an azabicyclo structure and salts or complexes thereof, amidine and salts or complexes thereof, compounds with a pyridine ring and salts or complexes thereof, phosphines and salts or complexes thereof, and compounds with a tertiary diamine structure and salts or complexes thereof. Catalyst B: One or more kinds of compounds selected from a group consisting of compounds comprising zinc. Adsorbent C: One or more kinds of compounds selected from a group consisting of oxides and hydroxides comprising at least one of magnesium, aluminum and silicon.

  本发明提供了一种（甲基）丙烯酸酯制备方法，其特征在于通过在使用催化剂A和催化剂B一起进行醇和单官能基（甲基）丙烯酸酯之间的酯交换反应制备（甲基）丙烯酸酯时，对酯交换反应产物进行与吸附剂C的接触处理。催化剂A：从含有氮杂双环结构的环状三级胺及其盐或络合物、胺嘧啶及其盐或络合物、含有吡啶环的化合物及其盐或络合物、膦及其盐或络合物、以及含有三级二胺结构的化合物及其盐或络合物中选择的一种或多种化合物。催化剂B：从含锌化合物中选择的一种或多种化合物。吸附剂C：从含有镁、铝和硅中至少一种的氧化物和氢氧化物中选择的一种或多种化合物。
• (Meth)acrylate manufacturing method
  申请人：TOAGOSEI CO., LTD.

  公开号：US10266476B2

  公开（公告）日：2019-04-23

  The present invention provides a (meth)acrylate manufacturing method characterized in that when manufacturing a (meth)acrylate by an ester exchange reaction between an alcohol and a monofunctional (meth)acrylate using catalyst A and catalyst B together, contact treatment of the ester exchange reaction product with adsorbent C is performed. Catalyst A: One or more kinds of compounds selected from a group consisting of cyclic tertiary amines with an azabicyclo structure and salts or complexes thereof, amidine and salts or complexes thereof, compounds with a pyridine ring and salts or complexes thereof, phosphines and salts or complexes thereof, and compounds with a tertiary diamine structure and salts or complexes thereof. Catalyst B: One or more kinds of compounds selected from a group consisting of compounds comprising zinc. Adsorbent C: One or more kinds of compounds selected from a group consisting of oxides and hydroxides comprising at least one of magnesium, aluminum and silicon.

  本发明提供了一种(甲基)丙烯酸酯的制造方法，其特征在于当使用催化剂A和催化剂B一起通过醇和单官能团(甲基)丙烯酸酯之间的酯交换反应制造(甲基)丙烯酸酯时，用吸附剂C对酯交换反应产物进行接触处理。催化剂 A：一种或多种选自以下组别的化合物：具有氮杂双环结构的环状叔胺及其盐或络合物、脒及其盐或络合物、具有吡啶环的化合物及其盐或络合物、膦及其盐或络合物、具有叔二胺结构的化合物及其盐或络合物。催化剂 B：一种或多种从含锌化合物组中选出的化合物。吸附剂 C：一种或多种选自氧化物和氢氧化物（至少包括镁、铝和硅中的一种）的化合物。
• PHOTOCURABLE RESIN COMPOSITION
  申请人：Hitachi Chemical Co., Ltd.

  公开号：EP1794199B1

  公开（公告）日：2010-01-13
• Photocurable Resin Composition
  申请人：Hayashi Katsunori

  公开号：US20080318075A1

  公开（公告）日：2008-12-25

  A photocurable resin composition comprising a (meth)acrylate ester with a sulfur content of no more than 5 ppm is disclosed. This photocurable resin composition is preferably used in a coating material or an adhesive, or in an adhesive layer or a protective layer formed on top of the metal layer of an optical disk.