N-[3-[[2-bromo-6-chloro-4-[1,2,2,2-tetrafluoro-1-(trifluoromethyl)ethyl]phenyl]carbamoyl]-2-methoxyphenyl]-N-ethylpyridine-4-carboxamide | 1429513-53-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-[3-[[2-bromo-6-chloro-4-[1,2,2,2-tetrafluoro-1-(trifluoromethyl)ethyl]phenyl]carbamoyl]-2-methoxyphenyl]-N-ethylpyridine-4-carboxamide
• 英文别名: N-[3-[[2-bromo-6-chloro-4-[1,2,2,2-tetrafluoro-1-(trifluoromethyl)ethyl]phenyl]carbamoyl]-2-methoxy-phenyl]-N-ethyl-pyridine-4-carboxamide；N-[3-[[2-bromo-6-chloro-4-(1,1,1,2,3,3,3-heptafluoropropan-2-yl)phenyl]carbamoyl]-2-methoxyphenyl]-N-ethylpyridine-4-carboxamide
• CAS: 1429513-53-0
• 化学式: C₂₅H₁₈BrClF₇N₃O₃
• 分子量: 656.782
• InChiKey: YWARLYUENDCVEU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.6
• 重原子数：
  40
• 可旋转键数：
  7
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.24
• 拓扑面积：
  71.5
• 氢给体数：
  1
• 氢受体数：
  11

反应信息

• 作为产物：
  描述：

  2-甲氧基-3-硝基苯甲酸甲酯 在 草酰氯 、 lithium hydroxide monohydrate 、 palladium 10% on activated carbon 、 甲酸铵 、 三乙胺 、 N,N-二甲基甲酰胺 、 sodium hydroxide 作用下， 以 四氢呋喃 、 二氯甲烷 、 水 、 1,2-二氯乙烷 、 异丙醇 为溶剂， 反应 21.67h， 生成 N-[3-[[2-bromo-6-chloro-4-[1,2,2,2-tetrafluoro-1-(trifluoromethyl)ethyl]phenyl]carbamoyl]-2-methoxyphenyl]-N-ethylpyridine-4-carboxamide
  参考文献：
  名称：

  [EN] PROCESS FOR THE PREPARATION OF AMIDES FROM HINDERED ANILINES CONTAINING A PERHALOALKYL GROUP
  [FR] PROCÉDÉ POUR LA PRÉPARATION D'AMIDES À PARTIR D'ANILINES ENCOMBRÉES CONTENANT UN GROUPE PERHALOALKYLE

  摘要：

  本发明提供了一种新颖且改进的工艺，用于以接近化学计量的酰化剂量生产含有全氟烷基的受阻胺类化合物，产率较高。

  公开号：

  WO2014161850A1

文献信息

• HETEROCYCLIC COMPOUND AND ARTHROPOD PEST CONTROL COMPOSITION CONTAINING SAME
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：US20210030003A1

  公开（公告）日：2021-02-04

  The present invention provides a compound that has an excellent control effect on arthropod pests, and is represented by formula (I) [wherein Q represents a group represented by Q1, or the like, n is 0, 1, or 2, R 2 represents a C1-C6 alkyl group which may optionally have one or more halogen atoms, or the like, Y a represents an oxygen atom, a sulfur atom, or NR 3a , G 1 represents a nitrogen atom or CR 5a , G 2 represents a nitrogen atom or CR 5b , A 2 represents a nitrogen atom or CR 4a , A 3 represents a nitrogen atom or CR 4b , A 4 represents a nitrogen atom or CR 4c , and R 3a , R 4a , R 4b , R 4c , R 5a , and R 5b represent a C1-C6 chain hydrocarbon group or the like, and T represents a C1-C10 chain hydrocarbon group which may optionally have one or more halogen atoms, or the like].

  本发明提供了一种对节肢动物害虫具有优异控制效果的化合物，其化学式表示为（I）[其中Q代表由Q1等表示的基团，n为0、1或2，R2代表可能含有一个或多个卤素原子等的C1-C6烷基基团，Ya代表氧原子、硫原子或NR3a，G1代表氮原子或CR5a，G2代表氮原子或CR5b，A2代表氮原子或CR4a，A3代表氮原子或CR4b，A4代表氮原子或CR4c，而R3a、R4a、R4b、R4c、R5a和R5b代表C1-C6链烃基团等，T代表可能含有一个或多个卤素原子等的C1-C10链烃基团]。
• HETEROCYCLIC COMPOUND AND HARMFUL ARTHROPOD CONTROLLING AGENT CONTAINING SAME
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：US20210084903A1

  公开（公告）日：2021-03-25

  The present invention provides a compound substituted with an excellent control effect against a harmful arthropod, which is represented by formula (I) Het-Q  (I) wherein Q represents a group represented by Q1, etc., Het represents a group represented by Het1, etc., R 2 represents a C1-C6 alkyl group, etc., G 1 represents a nitrogen atom or CR 3a , G 2 represents a nitrogen atom or CR 3b , G 3 represents a nitrogen atom or CR 3c , G 4 represents a nitrogen atom or CR 3d , R 3a , R 3b , R 3c , and R 3d are identical to or different from each other and represent a C1-C6 chain hydrocarbon group, etc., n represents 0, 1, or 2, T represents a C1-C10 chain hydrocarbon group substituted with one or more halogen atoms, etc., A 2 represents a nitrogen atom or CR 4a , A 3 represents a nitrogen atom or CR 4b , R 4a and R 4b are identical to or different from each other and represent a C1-C6 chain hydrocarbon group, W 1 represents an oxygen atom, etc., and R 6 represents a C1-C6 chain hydrocarbon group, etc.

  本发明提供了一种具有对有害节肢动物具有优异控制效果的化合物，其表示为公式（I）Het-Q（I），其中Q代表由Q1等表示的基团，Het代表由Het1等表示的基团，R2代表C1-C6烷基基团等，G1代表氮原子或CR3a，G2代表氮原子或CR3b，G3代表氮原子或CR3c，G4代表氮原子或CR3d，R3a、R3b、R3c和R3d彼此相同或不同且代表C1-C6链烃基团等，n代表0、1或2，T代表一个或多个卤原子取代的C1-C10链烃基团等，A2代表氮原子或CR4a，A3代表氮原子或CR4b，R4a和R4b彼此相同或不同且代表C1-C6链烃基团，W1代表氧原子等，R6代表C1-C6链烃基团等。
• HETEROCYCLIC COMPOUNDS AND NOXIOUS ARTHROPOD CONTROL AGENT CONTAINING SAME
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：US20210059255A1

  公开（公告）日：2021-03-04

  The present invention provides a compound that have excellent harmful arthropod controlling effects, the compounds being represented by formula (I) [wherein Q represents a group represented by formula Q1 or the like, Z represents an oxygen atom or a sulfur atom, A 1 represents a nitrogen atom or CR 6a , A 2 represents a nitrogen atom or CR 6b , A 3 represents a nitrogen atom or CR 6c , A 4 represents CR 1a or the like, A 5 represents a nitrogen atom or CR 6e or the like, A 6 represents a nitrogen atom or CR 6f , R 6a represents a hydrogen atom or the like, R 6b represents a C1-C6 chain hydrocarbon group or the like, R 6c , R 6e , R 6f are identical to or different from each other, and each represents a C1-C6 chain hydrocarbon group or the like, R 1a represents a C1-C6 chain hydrocarbon group or the like, R 2 represents a C1-C6 chain hydrocarbon group or the like, R 3 represents a C1-C6 chain hydrocarbon group or the like, and n is 0, 1 or 2] or its N oxide compound.

  本发明提供了一种具有优异有害节肢动物控制效果的化合物，该化合物由式（I）表示【其中Q表示由式Q1或类似物表示的基团，Z表示氧原子或硫原子，A1表示氮原子或CR6a，A2表示氮原子或CR6b，A3表示氮原子或CR6c，A4表示CR1a或类似物，A5表示氮原子或CR6e或类似物，A6表示氮原子或CR6f，R6a表示氢原子或类似物，R6b表示C1-C6链烃基或类似物，R6c，R6e，R6f彼此相同或不同，且各自表示C1-C6链烃基或类似物，R1a表示C1-C6链烃基或类似物，R2表示C1-C6链烃基或类似物，R3表示C1-C6链烃基或类似物，n为0、1或2】或其N氧化物化合物。
• PHENYLPYRAZOLE COMPOUND AND METHOD FOR CONTROLLING PLANT DISEASE
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：US20210321614A1

  公开（公告）日：2021-10-21

  The present invention provides a method for controlling a plant disease which comprises applying a compound represented by formula (I) [wherein Z represents a C1-C6 chain hydrocarbon group and the like, R 1 and R 2 are identical to or different from each other and represent a hydrogen atom or a fluorine atom, and R 3 , R 4 , R 5 , R 6 and R 7 are identical to or different from each other and represent a C1-C6 chain hydrocarbon group and the like] to a plant or a soil, which has excellent control efficacies against plant diseases.

  本发明提供了一种用于控制植物疾病的方法，包括将由式（I）表示的化合物应用于植物或土壤，其中Z代表C1-C6链烃基等，R1和R2相同或不同，代表氢原子或氟原子，R3、R4、R5、R6和R7相同或不同，代表C1-C6链烃基等，该方法对植物疾病具有优异的控制效果。
• PROCESS FOR THE PREPARATION OF AMIDES FROM HINDERED ANILINES CONTAINING A PERHALOALKYL GROUP
  申请人：SYNGENTA PARTICIPATIONS AG

  公开号：US20160168097A1

  公开（公告）日：2016-06-16

  The present invention provides a novel and improved process for the production of the production of hindered anilines containing perfluoroalky groups in good yield any by using close to stoichiometric amounts of acylating agent.

  本发明提供了一种新颖且改进的生产含有全氟烷基的阻碍胺类化合物的方法，该方法可以使用接近化学计量的酰化试剂量，且产率良好。