(3aR,5S,6aR)-5-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-6-methanesulfonylmethyl-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxole | 134222-12-1

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (3aR,5S,6aR)-5-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-6-methanesulfonylmethyl-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxole
• CAS: 134222-12-1
• 化学式: C₁₄H₂₄O₇S
• 分子量: 336.406
• InChiKey: PNBMBIFBDVSIDE-UPUXHGCUSA-N

反应信息

• 作为产物：
  描述：

  (3aR,5S,6aR)-5-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-6-[1-methanesulfonyl-meth-(E)-ylidene]-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxole 在 hydrido(triphenylphosphine)copper(I) hexamer 作用下， 以88%的产率得到(3aR,5S,6aR)-5-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-6-methanesulfonylmethyl-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxole
  参考文献：
  名称：

  Synthesis of nucleoside sulfonates and sulfones

  摘要：

  Sulfonate analogues of adenine, cytidine and guanine monophosphates have been synthesized for the first time. The synthesis of ribose 3-sulfonate, a synthesis of sulfonyl disaccharides and dinucleotides and an improved synthesis of a ribose 3-sulfone is also reported.

  DOI：

  10.1016/s0040-4039(00)79642-0