[Mo2(μ-S)2O2(H2O)6](2+) | 146278-65-1

• 分子结构分类: 有机化合物 - 有机酸及其衍生物
• 英文名称: [Mo2(μ-S)2O2(H2O)6](2+)
• 英文别名: [Mo2O2(μ-S)2(H2O)6](2+)
• CAS: 146278-65-1
• 化学式: H₁₂Mo₂O₈S₂
• 分子量: 396.102
• InChiKey: LZELQCSRFABEIT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  hydroxide 、 [Mo2(μ-S)2O2(H2O)6](2+) 、 水 、 squarate dianion 以 水 为溶剂， 生成
  参考文献：
  名称：

  Assembly and Autochirogenesis of a Chiral Inorganic Polythioanion Möbius Strip via Symmetry Breaking

  摘要：

  Using [Mo2S2O2(H2O)(6)](2+) and squarate dianion, we synthesized the thiometalate ring compounds [(Mo2S2O2)(x)(OH)(y)(C4O4)(z)(Mo2O8)(o)(H2O)(p)](n-), where [x,y,z,o,p,n] = [7,14,2,0,2,4] for 1, [6,8,2,2,4,8] for 2, and [4,6,1,1,0,4] for both 3a and 3b, which are chiral and nonchiral isomers, respectively. Not only do the four thiometalate clusters show decreasing symmetry at the molecular level across the series, but the incorporation of the "addendum" {Mo2O8}(o) unit also allows the thiometalate ring to twist. The reaction initially yields the chiral molecule 3a with a twisted ring, which undergoes spontaneous resolution upon crystallization; the reaction mixture later yields the intrinsically nonchiral isomer 3b with a nontwisted ring. In addition, the compounds are able to promote the electrocatalytic evolution of hydrogen.

  DOI：

  10.1021/ja304371j
• 作为产物：
  描述：

  [Mo2O2(μ-S)2(OH)2(H2O)]5*2KI 在 Re(CO)5Cl 作用下， 以 盐酸 为溶剂， 以40%的产率得到Mo3(μ3-S)(μ2-O)3(H2O)9(4+)
  参考文献：
  名称：

  Reactions of molybdenum oxo-thioclusters with [Re(CO)5Cl]

  摘要：

  Reduction of [Mo2O2(mu-S)(2)(H2O)(6)](2+) with [Re(CO)(5)Cl] in 2 M HCl at 160 degrees C produces condensation of binuclear clusters with the formation of the{Mo-3(mu(3)-S)(mu-O)(3)}(4+) species, which was isolated and structurally characterized as {[Mo-3(mu(3)-S)(mu(2)-O)(3)(H2O)(6)Cl-3](2)CB[6]}Cl-2 center dot 10.88H(2)O (2) (CB[6] = C36H36N24O12) and [Mo-3(mu(3)-S)(mu(2)-O)(3)(acac)(3)(py)(3)] PF6 center dot 2C(6)H(5)CH(3) (3). Reaction of [Mo-3(mu(3)-S)(mu(2)-S)(mu(2)-O)(2)(H2O)(9)](4+) with [Re(CO)(5)Cl] produces cuboidal cluster [Mo-4(mu(3)-S)(4)(H2O)(12)](5+). (C) 2011 Published by Elsevier B.V.

  DOI：

  10.1016/j.ica.2011.10.005