| 827307-05-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 827307-05-1
• 化学式: C₃₆H₅₄CuN₂O₂
• 分子量: 610.383
• InChiKey: WIGUYPUCXWHYPU-OHUAMDITSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  copper(II) acetate monohydrate 、 N,N'-bis(3,5-di-t-butylsalicylidene)-1,6-diaminohexane 在 Et₃N 作用下， 以 甲醇 、 乙醇 、 氯仿 为溶剂， 以68%的产率得到
  参考文献：
  名称：

  Synthesis, spectroscopy, and electrochemistry of copper(II) complexes with N,N′-bis(3,5-di-t-butylsalicylideneimine)polymethylenediamine ligands

  摘要：

  Bulky salen CuLx derived from aliphatic polymethylene diamines, H2N-(CH2)(x)-NH2, where n = 2-6, and 3,5-di-t-butylsalicylaldehyde (H2Lx) and some corresponding tetrahydrosalan complexes (CuL'(x)) have been synthesized and characterized by their IR, UV-vis absorption and EPR spectra, by magnetic moments and by cyclic voltammetry in acetonitrile (for H2Lx) and DMF (for CuLx). Complexes CuLx and CuL'(x) are magnetically normal (mu(exp) = 1.83-1.91 mu(B)). EPR spectra CuLx characterized by the axial g and A(Cu) tensors with g(parallel to) > g(perpendicular to) and without N-14-shf resolution in CHCl3/toluene at 300 and 150 K. The CV studies on acetonitrile solutions of H2Lx revealed a well-defined quasi-reversible redox wave at E-1/2 = 0.95-1.15 V versus Ag/AgCl but CV of the CuLx complexes in DMF exhibit weak pronounced irreversible oxidation waves at E-pa(1) = 0.51 - 0.98 V and E-pa(2) = 1.16 - 1.33 V attributable to metal centered Cu(II/III) and ligand centered CuLx/CuLx.+ couples, respectively. A poorly defined wave was observed for the quasi-reversible reduction Cu(II)/Cu(I) at potentials less than -1.0 V. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.saa.2004.03.037