9-(oxiranylmethyl)carbazol-3-yl-carbaldehyde N-methyl-N-phenylhydrazone | 888031-81-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 9-(oxiranylmethyl)carbazol-3-yl-carbaldehyde N-methyl-N-phenylhydrazone
• CAS: 888031-81-0
• 化学式: C₂₃H₂₁N₃O
• 分子量: 355.439
• InChiKey: AJRRNFUDJIJQEM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.66
• 重原子数：
  27.0
• 可旋转键数：
  5.0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  33.06
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  4'4-二巯基二苯硫醚 、 9-(oxiranylmethyl)carbazol-3-yl-carbaldehyde N-methyl-N-phenylhydrazone 在 三乙胺 作用下， 以 丁酮 为溶剂， 反应 24.0h， 以19.6%的产率得到4,4'-di({3-[(2-methyl-2-phenylhydrazine-1-ylidene)methyl]carbazole-9-yl}-2-hydroxypropylsulfanyl)diphenylsulfane
  参考文献：
  名称：

  Glass-forming hole-transporting carbazole-based hydrazone monomers, polymers, and twin compounds

  摘要：

  The synthesis, optical. thermal, and photoelectrical properties of new carbazole-based hydrazone monomers, polymers, and twin compounds are reported. All the synthesized materials are capable of glass formation. Their glass transition temperatures range from 27 to 90 degrees C. The ionization potentials of the films of carbazole-based hydrazones measured by the electron photoemission technique range from 5.18 to 5.48 eV. Hole-drift mobilities in the amorphous films of the synthesized hydrazone monomers measured by the time-of-flight technique at room temperature reach 10(-4) cm(2)/(V s) at high applied electric fields. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.reactfunctpolym.2009.10.008
• 作为产物：
  描述：

  9-(环氧-2-甲基)-9H-咔唑 在 盐酸 、 copper(ll) sulfate pentahydrate 、 四丁基硫酸氢铵 、 potassium hydroxide 、 三氯氧磷 作用下， 以 1,4-二氧六环 、 甲醇 、 水 为溶剂， 反应 113.0h， 生成 9-(oxiranylmethyl)carbazol-3-yl-carbaldehyde N-methyl-N-phenylhydrazone
  参考文献：
  名称：

  Glass-forming hole-transporting carbazole-based hydrazone monomers, polymers, and twin compounds

  摘要：

  The synthesis, optical. thermal, and photoelectrical properties of new carbazole-based hydrazone monomers, polymers, and twin compounds are reported. All the synthesized materials are capable of glass formation. Their glass transition temperatures range from 27 to 90 degrees C. The ionization potentials of the films of carbazole-based hydrazones measured by the electron photoemission technique range from 5.18 to 5.48 eV. Hole-drift mobilities in the amorphous films of the synthesized hydrazone monomers measured by the time-of-flight technique at room temperature reach 10(-4) cm(2)/(V s) at high applied electric fields. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.reactfunctpolym.2009.10.008