| 77984-64-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• CAS: 77984-64-6
• 化学式: C₄₈H₁₀₈O₁₂P₄Pd
• 分子量: 1107.69
• InChiKey: OZNPZEYEKJLIQK-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  、 足球烯 以 甲苯 为溶剂， 生成
  参考文献：
  名称：

  New organometallic complexes of buckminsterfullerene having π-bondend nickel, palladium, or platinum with triorganophosphite ligands, and their characterisation

  摘要：

  We have prepared a series of novel pi-complexes of fullerene C-60 of the types [C-60{M(P(OR)(3))(2)}(n)], (M = Ni, Pd, or Pt; R = Ph, Bu, or Et; n = 1 or 2). The compounds have been characterised by mass spectrometry, electronic spectroscopy and proton, carbon, and phosphorus NMR spectroscopy. The sensitivity of these compounds to air increases greatly in the series Pt < Pd << Ni. Unlike analogous phosphine derivatives, the phosphite species do not readily form complexes with more than two metal atoms attached to the fullerene cage. In contrast with many pi-bonded fullerene derivatives, most of the compounds show molecular ions in the FAB mass spectrum.

  DOI：

  10.1016/0022-328x(94)05249-b