| 157768-34-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• CAS: 157768-34-8
• 化学式: C₁₄H₂₃CuN₄O*ClO₄
• 分子量: 426.359
• InChiKey: QLAOCLILYVSYEQ-UHFFFAOYSA-L

反应信息

• 作为反应物：
  描述：

  、 sodium perchlorate 在 HCl 作用下， 以 乙醇 为溶剂， 生成
  参考文献：
  名称：

  Dalton communications. Partial hydrolysis of a Schiff-base tripodal ligand induced by copper(II) salts: crystal structure of the product from reaction with copper(II) perchlorate

  摘要：

  The reaction of Cu(ClO4)2 or Cu(NO3)2 with a potentially heptadentate Schiff-base tripod derived from tris(2-aminoethyl)amine and 2-hydroxyacetophenone occurs with accompanying hydrolysis of the ligand; single-crystal X-ray structure analysis of the product involving Cu (ClO4)2 shows the ligand to exist in a zwitterionic form and provide a near square-planar environment for the copper(II) cation.

  DOI：

  10.1039/dt9940002213
• 作为产物：
  描述：

  在 triethylamine 作用下， 以 乙醇 为溶剂， 以65%的产率得到
  参考文献：
  名称：

  Dalton communications. Partial hydrolysis of a Schiff-base tripodal ligand induced by copper(II) salts: crystal structure of the product from reaction with copper(II) perchlorate

  摘要：

  The reaction of Cu(ClO4)2 or Cu(NO3)2 with a potentially heptadentate Schiff-base tripod derived from tris(2-aminoethyl)amine and 2-hydroxyacetophenone occurs with accompanying hydrolysis of the ligand; single-crystal X-ray structure analysis of the product involving Cu (ClO4)2 shows the ligand to exist in a zwitterionic form and provide a near square-planar environment for the copper(II) cation.

  DOI：

  10.1039/dt9940002213