[Cu(bis(3,5-dimethyl-1-pyrazolyl)methane)2(NO3)]NO3 | 1023596-20-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: [Cu(bis(3,5-dimethyl-1-pyrazolyl)methane)2(NO3)]NO3
• CAS: 1023596-20-4；71667-07-7
• 化学式: C₂₂H₃₂CuN₉O₃*NO₃
• 分子量: 596.105
• InChiKey: BZCNTJRMIWPOGH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  copper(II) nitrate trihydrate 、 1-[(3,5-二甲基吡唑-1-基)甲基]-3,5-二甲基吡唑 以 二氯甲烷 、 丙酮 为溶剂， 以19%的产率得到[Cu(bis(3,5-dimethyl-1-pyrazolyl)methane)2(NO3)]NO3
  参考文献：
  名称：

  Copper(II) complexes with neutral bis(pyrazolyl)methane ligands: The influence of steric hindrance on their structures and properties

  摘要：

  By using the neutral bidentate nitrogen-containing ligands; bis(3,5-dimethyl-1-pyrazolyl)methane (L0"), bis(3,5-diisopropyl-1-pyrazolyl)methane (L1"), bis(3-tertiary-butyl-5-isopropyl-1-pyrazolyl)methane (L3"), and bis(3,5-ditertiary-butyl-1-pyrazolyl)methane (L4"), the copper(II) nitrato complexes [Cu(L0")(2)(NO3)]NO3 (1NO(3)), [Cu(L0")(NO3)(2)] (2), [Cu(L1")(NO3)(2)] (3), [Cu(L3")(NO3)(2)] (4), and [Cu(L4")(NO3)(2)] (5), chloro complexes [Cu(L0")(2)Cl](2)(CuCl4) (6CuCl(4)), [Cu(L0")(2)Cl](2)(Cu2Cl6) (6Cu(2)Cl(6)), [Cu(L1")Cl-2] (7), and [Cu(L3")Cl-2] (8), nitrito complexes [Cu(L0")(ONO)(2)] (9) and [Cu(L1")(ONO)(2)] (10), and the complexes with perchlorate ions [Cu(L0")(2)(CH3OH)](ClO4)(2) (11ClO(4)) and [Cu(L1")(2)(H2O)](ClO4)(2) (12ClO(4)) were systematically synthesized and fully characterized by X-ray crystallography and by IR, far-IR, UV-Vis absorption, and ESR spectroscopy. In comparison with the obtained complexes with four bis(pyrazolyl)methanes having different bulkiness at pyrazolyl rings, the second coordination sphere effects on the ligands are discussed in detail. Moreover, the structures and physicochemical properties of these obtained complexes are compared with those of the related complexes with the neutral tridentate tris(pyrazolyl)methane ligand. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2008.01.019