sodium borohydride 18-crown-6 water | 1078570-37-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: sodium borohydride 18-crown-6 water
• CAS: 1078570-37-2
• 化学式: BH₄*C₁₂H₂₄O₆*H₂O*Na
• 分子量: 320.167
• InChiKey: YEWXICTXGPCRKI-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  sodium tetrahydroborate 、 18-冠醚-6 以 乙腈 为溶剂， 生成 sodium borohydride 18-crown-6 water
  参考文献：
  名称：

  Complexes of sodium and lithium borohydrides with macrocyclic polyethers

  摘要：

  A method for the synthesis of complexes of sodium and lithium borohydrides with crown ethers is proposed. The complexes of sodium borohydride with benzo- 15-crown-5, 4'-aminobenzo- 15-crown-5, dibenzo-18-crown-6, and diaza-18-crown-6 and the complexes of lithium borohydride with benzo- 15-crown-5 and dibenzo-18-crown-6 are synthesized. These complexes can be used for the preparation of hydrogen in their reactions with methanol. The complex formation does not affect the purity of hydrogen formed.

  DOI：

  10.1134/s1070328407080027