Pt(0)(isopropylidene-2,3-dihydroxy-1,4-bis-diphenylphosphinobutane)2 | 84800-80-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: Pt(0)(isopropylidene-2,3-dihydroxy-1,4-bis-diphenylphosphinobutane)2
• CAS: 84800-80-6
• 化学式: C₆₂H₆₄O₄P₄Pt
• 分子量: 1192.16
• InChiKey: QZWVVORKZFNQKF-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  Pt(0)(isopropylidene-2,3-dihydroxy-1,4-bis-diphenylphosphinobutane)2 、 足球烯 以 甲苯 为溶剂， 以67%的产率得到
  参考文献：
  名称：

  Chiral derivatives ofexo-metallofulierenes: Synthesis and X-ray study of solvate of platinumfullerene cluster with cyclooctene, ?2-C60Pt[(+)-D1OP] � C8H14

  摘要：

  A novel optically active exo-metallofullerene derivative, eta(2)-C60Pt[(+)-DIOP] (1) (DIOP is 2,3-o,o'-isopropylidene-2,3-dihydroxy-1,4-bis(diphenylphosphinobutane)), is formed as a result of the cleavage of the chelate metallocycle in Pt[(+)-DIOP](2) and the substitution of the bidentate (+)-DIOP ligand with C-60. Cluster 1 was also obtained by replacement of the phosphine ligands in eta(2)-C60Pt(PPh(3))(2) by (+)-DIOP. Compound 1 was identified by its electronic absorption spectra, P-31 NMR spectra, and the elemental analysis data. A single-crystal X-ray study of the 1 cyclooctene solvate, eta(2)-C-60,Pt[(+)-DIOP]. C8H14 was performed. Packing of the fullerene cores in a crystal of 1 . C8H14 corresponds to the diamond structure subjected to the significant orthorhombic distortions.

  DOI：

  10.1007/bf01431621