4-[(E)-2-(4-Propoxy-phenyl)-vinyl]-pyridine | 116223-45-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 4-[(E)-2-(4-Propoxy-phenyl)-vinyl]-pyridine
• 英文别名: 4-[(E)-2-(4-propoxyphenyl)ethenyl]pyridine
• CAS: 116223-45-1
• 化学式: C₁₆H₁₇NO
• 分子量: 239.317
• InChiKey: MBKVZBGSNBOSLG-ONEGZZNKSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  18
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.19
• 拓扑面积：
  22.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  carbanide,diiodoplatinum(2+) 、 4-[(E)-2-(4-Propoxy-phenyl)-vinyl]-pyridine 以 二氯甲烷 为溶剂， 以75%的产率得到carbanide;diiodoplatinum(2+);4-[(E)-2-(4-propoxyphenyl)ethenyl]pyridine
  参考文献：
  名称：

  Angular (cis-stilbazole) geometry in octahedral dimethyldihalidoplatinum(IV) complexes: potential as metallomesogens and X-ray structure of [PtMe2I2(NC5H4CHCHC6H4OC7H15)2]

  摘要：

  The synthesis and characterisation of a series of octahedral dimethyldihalidoplatinum(IV) complexes of 4-alkoxy-4'-stilbazoles with the general formula [PtMe2X2(NC5H4CH=CHC6H4OR)(2)] (X = I or Br, R = n-alkyl) is described. Some of the complexes show mesogenic behaviour. The structure of the complex with X = I and R = C7H15 has been determined by X-ray crystallography, revealing a cis coordination geometry with respect to both the methyl and the substituted 4-alkoxy-4'-stilbazole (n-OST) ligands. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(01)01332-8
• 作为产物：
  描述：

  4-乙烯基吡啶 、 1-碘-4-丙氧基苯 在 palladium diacetate 三乙胺 作用下， 以 乙腈 为溶剂， 反应 72.0h， 生成 4-[(E)-2-(4-Propoxy-phenyl)-vinyl]-pyridine
  参考文献：
  名称：

  Mesomorphic Metal Complexes Derived from 4-Alkyl-oxystilbazoles

  摘要：

  DOI：

  10.1080/10587259208038507

文献信息

• Melt syntheses of some [PtCl2L2] complexes
  作者：Duncan W. Bruce、Bertrand Donnio、Andrew A. Maggs、Julian R. Marsden

  DOI：10.1016/s0020-1693(00)80914-7

  日期：1991.10

  Reaction of PtCl2 in the melt of a ligand, L, leads in most cases to the complex [PtCl2L2] in good yield, with short reaction time. In all cases either pure cis or pure trans isomer is produced, depending on the nature of L.