carbanide,diiodoplatinum(2+) | 31926-38-2

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 卤代烷
• 英文名称: carbanide,diiodoplatinum(2+)
• 英文别名: dimethyl platinum (2+); diiodide；Dimethyl-platin(2+); Dijodid；Dimethylplatindiiodid；Diioddimethylplatin
• CAS: 31926-38-2
• 化学式: C₂H₆I₂Pt
• 分子量: 478.959
• InChiKey: QDLZINCIUHVXCS-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  2.94
• 重原子数：
  5.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  carbanide,diiodoplatinum(2+) 、 trans-4-butoxy-4'-stilbazole 以 二氯甲烷 为溶剂， 以66%的产率得到4-[(E)-2-(4-butoxyphenyl)ethenyl]pyridine;carbanide;diiodoplatinum(2+)
  参考文献：
  名称：

  Angular (cis-stilbazole) geometry in octahedral dimethyldihalidoplatinum(IV) complexes: potential as metallomesogens and X-ray structure of [PtMe2I2(NC5H4CHCHC6H4OC7H15)2]

  摘要：

  The synthesis and characterisation of a series of octahedral dimethyldihalidoplatinum(IV) complexes of 4-alkoxy-4'-stilbazoles with the general formula [PtMe2X2(NC5H4CH=CHC6H4OR)(2)] (X = I or Br, R = n-alkyl) is described. Some of the complexes show mesogenic behaviour. The structure of the complex with X = I and R = C7H15 has been determined by X-ray crystallography, revealing a cis coordination geometry with respect to both the methyl and the substituted 4-alkoxy-4'-stilbazole (n-OST) ligands. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(01)01332-8

文献信息

• The synthesis of olefin, carbonyl and thiolate complexes of platinum(IV) in the [η5-C5Me5)Pt(IV)] system. Crystal and molecular structure of (η2-C5Me5)PtMe2[S(p-CH3(C6H4]
  作者：William A. Howard、Robert G. Bergman

  DOI：10.1016/s0277-5387(97)00397-5

  日期：1998.3

  A number of Cp*PtMe2X and Cp*PtMe2(L)(+)(OTf)(-) complexes have been prepared [Cp* = eta(5)-C5Me5; OTf = OSO2CF3; X = OTf, I, N-3, S(p-tol); L = CO, C2H4, CH2=CHMe, NH3, NH2But]. The complexes Cp*PtMe2(CO)(+)(OTf)(-), Cp*PtMe2(C2H4)(+)(OTf)(-), and Cp*PtMe2(CH2=CHMe)(+)(OTf)(-) represent a rare type of compound in which a pi acid ligand is coordinated to a high valent metal center predominantly through sigma-donation and pi-backbonding plays only a limited role in the metal-ligand interaction. The arylthiolate complex, Cp*PtMe2[S(p-tol)], has been structurally characterized by X-ray diffraction. (C) 1998 Elsevier Science Ltd. All rights reserved.