[Pb(aminomethylphosphonate)(NO3)]n | 1042385-18-1

• 分子结构分类: 有机化合物 - 有机酸及其衍生物
• 英文名称: [Pb(aminomethylphosphonate)(NO3)]n
• 英文别名: [Pb(ampa)(NO3)]n
• CAS: 1042385-18-1
• 化学式: CH₅NO₃P*NO₃*Pb
• 分子量: 379.234
• InChiKey: UWAIFLHQDKIPFO-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -3.52
• 重原子数：
  11.0
• 可旋转键数：
  1.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  157.03
• 氢给体数：
  1.0
• 氢受体数：
  6.0

反应信息

• 作为产物：
  描述：

  lead(II) nitrate 、 氨甲基膦酸 以 水 为溶剂， 以18%的产率得到[Pb(aminomethylphosphonate)(NO3)]n
  参考文献：
  名称：

  Synthesis of homo and hetero metal-phosphonate frameworks from bi-functional aminomethylphosphonic acid

  摘要：

  The reaction between aminomethylphosphonic acid (ampa) and the metal salts of Zn, Cd, Hg, Pb, Ag, and Cu afforded seven metal-phosphonate polymers with unique structural features and includes the synthesis of a bimetallic metal-organic framework (Cu/Ag). The characterization of these metal phosphonates is reported by means of infrared spectroscopy, H-1-NMR, P-31-NMR, X-ray crystallography, energy dispersive X-ray (EDX), and thermogravimetric analysis (TGA). Individual structural features are compared based on the preferred coordination mode of ampa and the geometrical requirements for each metallic center that manipulates the structural motif. (c) 2008 Elsevier Inc. All rights reserved.

  DOI：

  10.1016/j.jssc.2008.03.023