1,5-naphthaquinone | 51583-62-1

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1,5-naphthaquinone
• 英文别名: 1,5-Naphtochinon；1.5-Naphthochinon；1,5 naphthoquinone；1,5-Naphthalenedione；naphthalene-1,5-dione
• CAS: 51583-62-1
• 化学式: C₁₀H₆O₂
• 分子量: 158.156
• InChiKey: UKYHUQYCBBUNIA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.3
• 重原子数：
  12
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  34.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  1,5-二羟基萘 在 oxoethoxomolybdenum(v)tetraphenylporphyrin 作用下， 生成 1,5-naphthaquinone
  参考文献：
  名称：

  双核钼(V)卟啉由苯二酚或萘二甲酸二价离子桥接：涉及电子转移的两个钼中心的协同配位平衡

  摘要：

  研究了钼卟啉与芳香二醇的反应。证实了两个羟基与钼中心的协同配位。

  DOI：

  10.1246/cl.1996.1109

文献信息

• CRYSTALLINE BIPYRIDINIUM RADICAL COMPLEXES AND USES THEREOF
  申请人：NORTHWESTERN UNIVERSITY

  公开号：US20150191470A1

  公开（公告）日：2015-07-09

  Described herein are methods of generating 4,4′-bipyridinium radical cations (BIPY •+ ), and methods for utilizing the radical-radical interactions between two or more BIPY •+ radical cations that ensue for the creation of novel materials for applications in nanotechnology. Synthetic methodologies, crystallographic engineering techniques, methods of physical characterization, and end uses are described.

  本文描述了生成4,4′-联吡啶正离子（BIPY•+）的方法，以及利用两个或更多BIPY•+正离子之间的自由基-自由基相互作用来创造用于纳米技术应用的新材料的方法。描述了合成方法、晶体工程技术、物理特性表征方法和最终用途。
• [EN] VIOLOGEN-BASED ROTAXANES<br/>[FR] ROTAXANES À BASE DE VIOLOGÈNE
  申请人：UNIV NORTHWESTERN

  公开号：WO2017132485A1

  公开（公告）日：2017-08-03

  Disclosed herein are nanoactuating rotaxanes comprsing a threading component, the threading component comprising a oligoviologen, and at least two macrocylic components, wherein the oligoviologen is threaded through each of the macrocylic components. Also disclosed are methods for making the rotaxanes.

  本文披露的是一种纳米作动轮烯，包括一个穿线组件，该穿线组件包括一个寡聚噻吩和至少两个大环组分，其中寡聚噻吩穿过每个大环组分。还披露了制备该轮烯的方法。
• Method for preparing light-absorbing polymeric compositions
  申请人：——

  公开号：US20040195552A1

  公开（公告）日：2004-10-07

  The present invention recites a method comprising reacting in a solvent in the presence of a base a) at least one diacidic monomer comprising about 1 to 100 mole % of at least one light-absorbing monomer having a light absorption maximum between about 300 nm and about 1200 nm and 99-0 mole % of a non-light absorbing monomer which does not absorb significant light at wavelengths above 300 nm or has a light absorption maximum below 300 nm, with b) an organic compound of Formula II X—B—X 1 wherein B is a divalent organic radical to form a light absorbing composition comprising a mixture of a polymer having the formula 1 and a cyclic compound having the general formula 2 wherein B is as defined above; n is at least 2, m is 1, 2, 3 or 4 and A comprises the residue of a diacidic monomer comprising about 1 to 100 mole % of at least one light-absorbing monomer having a light absorption maximum between about 300 nm and about 1000 nm and wherein the remaining portion of A comprises the residue of a non-light absorbing monomer which does not absorb significant light at wavelengths above 300 nm or has a light absorption maximum below 300 nm.

  本发明涉及一种方法，包括在溶剂中，在碱的存在下反应：a）至少一种二酸单体，其中包括约1至100摩尔％的至少一种具有在300nm至1200nm之间的光吸收最大值的光吸收单体和99-0摩尔％的不吸收在300nm以上波长处的显著光或具有在300nm以下的光吸收最大值的非光吸收单体；b）式IIX-B-X1的有机化合物，其中B是二价有机基团，以形成一种光吸收组合物，该组合物包括具有式1的聚合物和具有一般式2的环状化合物，其中B如上所定义；n至少为2，m为1、2、3或4，A包括约1至100摩尔％的至少一种具有在300nm至1000nm之间的光吸收最大值的光吸收单体的残基，其中A的其余部分包括不吸收在300nm以上波长处的显著光或具有在300nm以下的光吸收最大值的非光吸收单体的残基。
• Noncovalent functionalization of nanotubes
  申请人：Stoddart Fraser J.

  公开号：US20050043503A1

  公开（公告）日：2005-02-24

  Nanotubes are treated with poly(5-alkoxy-m-phenylenevinylene)-co-[(2,5-dioctyloxy-p-phenylene)vinylene]} (PAmPV) polymers and derivatives thereof to provide noncovalent functionalization of the nanotubes which increases solubility and enhances other properties.

  纳米管经过聚（5-烷氧基-m-苯乙烯基）-共-[(2,5-二辛氧基-p-苯乙烯基)]}（PAmPV）聚合物及其衍生物处理，以提供纳米管的非共价功能化，从而增加其溶解度并增强其他性能。
• Resinous particles, method for production thereof, and uses therefor
  申请人：NIPPON SHOKUBAI CO., LTD.

  公开号：EP0575143A2

  公开（公告）日：1993-12-22

  A method for the production of resinous particles which comprises subjecting a polymeric monomer having (meth)acryl type monomer as a main component to aqueous suspension polymerisation in the presence of a compound which is substantially insoluble in water and sparingly soluble in the polymeric monomer. The compound has at least one structural unit selected from -SH, -S-S-, -COOH, -NO₂, and -OH.

  一种生产树脂颗粒的方法，包括将一种以（甲基）丙烯酸类单体为主要成分的聚合单体，在一种基本不溶于水且极少溶于聚合单体的化合物存在下进行水悬浮聚合。该化合物至少有一个结构单元选自-SH、-S-S-、-COOH、-NO₂和-OH。