4-((R)-12-{5-[2-(5-Dodecyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-ethyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-2,8-dihydroxy-dodecyl)-6-methyl-2-phenyl-2H-pyridazin-3-one | 216580-06-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: 4-((R)-12-{5-[2-(5-Dodecyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-ethyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-2,8-dihydroxy-dodecyl)-6-methyl-2-phenyl-2H-pyridazin-3-one
• CAS: 216580-06-2
• 化学式: C₄₇H₇₈N₂O₇
• 分子量: 783.146
• InChiKey: ZSTCJHBZKRASFZ-FMURZEQDSA-N

反应信息

• 作为反应物：
  描述：

  甲氧基-三氟甲基苯 、 4-((R)-12-{5-[2-(5-Dodecyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-ethyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-2,8-dihydroxy-dodecyl)-6-methyl-2-phenyl-2H-pyridazin-3-one 在 4-二甲氨基吡啶 、 N,N'-二环己基碳二亚胺 作用下， 以 二氯甲烷 为溶剂， 反应 6.0h， 生成
  参考文献：
  名称：

  Linear acetogenins from Goniothalamus donnaiensis

  摘要：

  Four linear acetogenins, donhepocin (1), 34-epi-donhepocin (1'), donhexocin and donbutocin, have been isolated from the roots of Goniothalamus donnaiensis. 1 and 1', isolated as an epimeric pair, contain a rare gamma-hydroxymethyl-gamma-lactone. Their structures have been established on the basis of spectral and chemical evidence.

  DOI：

  10.1016/s0031-9422(97)00949-7
• 作为产物：
  描述：

  3-((R)-2,8,13,14,17,18-Hexahydroxy-triacontyl)-5-hydroxy-5-methyl-5H-furan-2-one 在 对甲苯磺酸 作用下， 以 乙醇 、 二氯甲烷 为溶剂， 反应 4.0h， 生成 4-((R)-12-{5-[2-(5-Dodecyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-ethyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-2,8-dihydroxy-dodecyl)-6-methyl-2-phenyl-2H-pyridazin-3-one
  参考文献：
  名称：

  Linear acetogenins from Goniothalamus donnaiensis

  摘要：

  Four linear acetogenins, donhepocin (1), 34-epi-donhepocin (1'), donhexocin and donbutocin, have been isolated from the roots of Goniothalamus donnaiensis. 1 and 1', isolated as an epimeric pair, contain a rare gamma-hydroxymethyl-gamma-lactone. Their structures have been established on the basis of spectral and chemical evidence.

  DOI：

  10.1016/s0031-9422(97)00949-7