| 1460264-42-9

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机氧化物
• CAS: 1460264-42-9
• 化学式: C₁₂H₂₂O₂
• 分子量: 198.305
• InChiKey: UQENBVLNQZBEAD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.62
• 重原子数：
  14.0
• 可旋转键数：
  5.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  18.46
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为产物：
  描述：

  cyclooctene 在 叔丁基过氧化氢 作用下， 以 乙腈 为溶剂， 反应 4.0h， 生成 氧化环辛烯 、 、 环辛-2-烯-1-醇 、 2-cycloocten-1-one
  参考文献：
  名称：

  Epoxidation of cyclooctene by host (nanocavity of zeolite-Y) guest (copper(II) complexes with 16- and 17-membered diaza dioxa macrocyclic Schiff bases) nanocomposite materials

  摘要：

  This work reports the synthesis and characterization of macrocyclic copper(II) complexes encapsulated within the nanopores of zeolite-Y. The obtained nanoparticles entrapped in the nanopores of zeolite have been characterized by FT-IR, UV-Vis, Diffuse reflectance spectra, spectroscopic techniques, molar conductance, magnetic moment data, XRD, thermal, and elemental analysis. The complexes (neat and encapsulated) were used for the oxidation of cyclooctene with tert-butyl hydroperoxide as oxidant in different solvents. The supported Cu[L-1](2+)-Y exhibited a moderate 81.9% selectivity for epoxidation with 84.2% conversion. The catalytic activity and selectivity of the heterogeneous catalysts do not change after recycling five times.

  DOI：

  10.1080/00958972.2013.798655