tetraaqua(4-amino-3,5-bis(3-pyridyl)-1,2,4-triazole)copper(II) sulfate monohydrate | 1239609-48-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: tetraaqua(4-amino-3,5-bis(3-pyridyl)-1,2,4-triazole)copper(II) sulfate monohydrate
• CAS: 1239609-48-3；1239609-52-9
• 化学式: C₁₂H₁₈CuN₆O₄*H₂O*O₄S
• 分子量: 487.938
• InChiKey: FESHAEIKIYZDDN-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  copper(ll) sulfate pentahydrate 、 水 、 双(吡啶-3-基)-4H-1,2,4-三唑-4-胺 以 水 为溶剂， 以78%的产率得到tetraaqua(4-amino-3,5-bis(3-pyridyl)-1,2,4-triazole)copper(II) sulfate monohydrate
  参考文献：
  名称：

  Four coordination polymers derived from 4-amino-3,5-bis(3-pyridyl)-1,2,4-triazole and copper sulfate

  摘要：

  The reaction of 4-amino-3,5-bis(3-pyridyl)-1,2,4-triazole (3-bpt) with copper sulfate in EtOH/H2O solvent yields four coordination polymers [Cu(3-bpt)(H2O)(4)](SO4)center dot H2O (1), [Cu(3-bpt)(H2O)(4)][Cu(3-bpt)(H2O)(3) (SO4)](SO4)center dot 7H(2)O (2), [Cu(3-bpt)(H2O)(3)(SO4)]center dot 2H(2)O (3) and [Cu(3-bpt)(H2O)(SO4)] (4), showing one-dimensional undulated chain, zigzag chain and two-dimensional network. The formations of compounds 1, 2 and 3 are controlled by the EtOH/H2O ratio. The synthesis of compound 4 may be controlled by the EtOH/H2O ratio and the temperature because it is prepared under solvothermal condition. The thermal properties have been investigated. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2010.05.011