| 960013-34-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• CAS: 960013-34-7
• 化学式: C₁₂H₂₄O₃
• 分子量: 216.321
• InChiKey: ZOCIBECZKHPCBE-WQLSENKSSA-N

反应信息

• 作为反应物：
  描述：

  在 manganese(IV) oxide 作用下， 以 正己烷 为溶剂， 反应 3.0h， 生成
  参考文献：
  名称：

  A facile synthetic method of α-quaternary-β,γ-unsaturated aldehydes via the stereoselective 1,4-elimination and α-regioselective Ferrier reaction

  摘要：

  The 1,4-elimination reaction of 2-substituted-(2Z)-4-methoxy-O-alkenyl acetals with n-butyllithium is shown to afford the 2-substituted-(1Z,3E)-O-1,3-dienyl acetals in high stereoselectivities. The Ferrier reaction of the O-1,3-dienyl acetals thus obtained provides the corresponding alpha-quaternary-beta,gamma-unsaturated aldehydes in excellent yields with high alpha-regioselectivities. (c) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2007.09.049
• 作为产物：
  描述：

  在 红铝 作用下， 以 甲苯 为溶剂， 反应 2.0h， 生成
  参考文献：
  名称：

  A facile synthetic method of α-quaternary-β,γ-unsaturated aldehydes via the stereoselective 1,4-elimination and α-regioselective Ferrier reaction

  摘要：

  The 1,4-elimination reaction of 2-substituted-(2Z)-4-methoxy-O-alkenyl acetals with n-butyllithium is shown to afford the 2-substituted-(1Z,3E)-O-1,3-dienyl acetals in high stereoselectivities. The Ferrier reaction of the O-1,3-dienyl acetals thus obtained provides the corresponding alpha-quaternary-beta,gamma-unsaturated aldehydes in excellent yields with high alpha-regioselectivities. (c) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2007.09.049