[Ag3(4-tert-butylbenzoate)(NH3)2] | 1352997-17-1

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: [Ag3(4-tert-butylbenzoate)(NH3)2]
• CAS: 1352997-17-1
• 化学式: C₃₃H₄₅Ag₃N₂O₆
• 分子量: 889.335
• InChiKey: XZQJDOCHQMUBGD-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  ammonium hydroxide 、 silver nitrate 、 对叔丁基苯甲酸 以 甲醇 、 乙醇 为溶剂， 以64%的产率得到[Ag3(4-tert-butylbenzoate)(NH3)2]
  参考文献：
  名称：

  A novel photoluminescent silver(I) wire supported by 4-tert-butylbenzoate and ligand-unsupported Ag⋯Ag interactions

  摘要：

  A novel silver(I) wire sustained by 4-tert-butylbenzoate and ligand-unsupported Ag center dot center dot center dot Ag interactions, [Ag-3(tbb)(3)(NH3)(2)](n) (1, Htbb=4-tert-butylbenzoic acid), has been synthesized and structurally characterized. In 1, three tbb ligands bind three Ag(I) ions to form a trinuclear subunit through ligand-supported Ag center dot center dot center dot Ag interactions. The inversion-related subunits are further extended to an infinite 1D zigzag Ag(I) wire through the ligand-unsupported Ag center dot center dot center dot Ag interactions. Argentophilicity (3.0283(14)-3.0910(17)angstrom) plays an important role in determining the infinite silver(I) wire. The thermal stability and luminescent behavior of 1 were also discussed. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2011.10.009