(2S,3S,4S,5R,6S)-3-[(2S,4aR,6R,7R,8R,8aR)-7-Azido-8-(4-oxo-pentanoyloxy)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yloxy]-6-hydroxy-4,5-bis-(4-methyl-benzoyloxy)-tetrahydro-pyran-2-carboxylic acid methyl ester | 180274-54-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (2S,3S,4S,5R,6S)-3-[(2S,4aR,6R,7R,8R,8aR)-7-Azido-8-(4-oxo-pentanoyloxy)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yloxy]-6-hydroxy-4,5-bis-(4-methyl-benzoyloxy)-tetrahydro-pyran-2-carboxylic acid methyl ester
• CAS: 180274-54-8
• 化学式: C₄₁H₄₃N₃O₁₅
• 分子量: 817.804
• InChiKey: UKDATISKRNSCPZ-APQZXAPASA-N

反应信息

• 作为反应物：
  描述：

  三氯乙腈 、 (2S,3S,4S,5R,6S)-3-[(2S,4aR,6R,7R,8R,8aR)-7-Azido-8-(4-oxo-pentanoyloxy)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yloxy]-6-hydroxy-4,5-bis-(4-methyl-benzoyloxy)-tetrahydro-pyran-2-carboxylic acid methyl ester 在 1,8-二氮杂双环[5.4.0]十一碳-7-烯 作用下， 以 二氯甲烷 为溶剂， 以74%的产率得到(2S,3S,4S,5R,6R)-3-[(2S,4aR,6R,7R,8R,8aR)-7-Azido-8-(4-oxo-pentanoyloxy)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yloxy]-4,5-bis-(4-methyl-benzoyloxy)-6-(2,2,2-trichloro-acetimidoyloxy)-tetrahydro-pyran-2-carboxylic acid methyl ester
  参考文献：
  名称：

  Tamura, Jun-Ichi; Neumann, Klaus W.; Ogawa, Tomoya, Liebigs Annalen, 1996, # 8, p. 1239 - 1257

  摘要：

  DOI：
• 作为产物：
  描述：

  (2S,3S,4S,5R,6S)-3-[(2S,4aR,6R,7R,8R,8aR)-7-Azido-8-(4-oxo-pentanoyloxy)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yloxy]-6-(4-methoxy-phenoxy)-4,5-bis-(4-methyl-benzoyloxy)-tetrahydro-pyran-2-carboxylic acid methyl ester 在 ammonium cerium(IV) nitrate 作用下， 以 乙腈 为溶剂， 反应 2.0h， 以94%的产率得到(2S,3S,4S,5R,6S)-3-[(2S,4aR,6R,7R,8R,8aR)-7-Azido-8-(4-oxo-pentanoyloxy)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yloxy]-6-hydroxy-4,5-bis-(4-methyl-benzoyloxy)-tetrahydro-pyran-2-carboxylic acid methyl ester
  参考文献：
  名称：

  Tamura, Jun-Ichi; Neumann, Klaus W.; Ogawa, Tomoya, Liebigs Annalen, 1996, # 8, p. 1239 - 1257

  摘要：

  DOI：