| 191589-56-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• CAS: 191589-56-7
• 化学式: C₅H₇O₂*C₈H₇O₂*Sn
• 分子量: 352.962
• InChiKey: WLOSRUWHOZZITC-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  2'-羟基苯乙酮 、 bis(2,4-pentanedionato)tin(II) 以 neat (no solvent) 为溶剂， 以81%的产率得到
  参考文献：
  名称：

  A New Method for Synthesizing Dialkoxytin(II) and Mono and Diaryloxytin(II) Compounds

  摘要：

  The reactions of bis(beta-diketonato)tin(II), such as bis(2,4-pentanedionato)tin(II), Sn(acac)(2), bis(1-ethoxy-1,3-butanedionato)tin(II), Sn(etac)2, and bis(1-methoxy-1,3-butanedionato)tin(II), Sn(mtac)(2), with sodium alkoxide (NaOR, R = CH3, C2H5) in alcohol/benzene at room temperature have been found to give the corresponding dialkoxytin(II) compounds. Sn(acac)(2) reacted also with o-substituted phenols [o-X-C6H4OH; X = CH3CO, CH3OC(O), CH3O, Cl, (CH3)(3)C] in a molar ratio of 1:2 at 90 degrees C to afford the corresponding monosubstituted tin(II) compound, [Sn(OC6H4-X)(acac)], but the reaction with C6H5OH produced only the diphenoxide, Sn(OC6H5)(2).

  DOI：

  10.1080/00945719708000227