43,44-Bis(phenylmethoxy)-3,6,9,12,15,18-hexaoxahexacyclo[18.15.7.126,30.137,41.02,32.019,24]tetratetraconta-1(35),2(32),19(24),20,22,26,28,30(44),33,37(43),38,40-dodecaene | 1207519-38-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 43,44-Bis(phenylmethoxy)-3,6,9,12,15,18-hexaoxahexacyclo[18.15.7.126,30.137,41.02,32.019,24]tetratetraconta-1(35),2(32),19(24),20,22,26,28,30(44),33,37(43),38,40-dodecaene
• 英文别名: 43,44-bis(phenylmethoxy)-3,6,9,12,15,18-hexaoxahexacyclo[18.15.7.126,30.137,41.02,32.019,24]tetratetraconta-1(35),2(32),19(24),20,22,26,28,30(44),33,37(43),38,40-dodecaene
• CAS: 1207519-38-7
• 化学式: C₅₂H₅₄O₈
• 分子量: 806.996
• InChiKey: ZSUYMAKJAYPTNL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.7
• 重原子数：
  60
• 可旋转键数：
  6
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.31
• 拓扑面积：
  73.8
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  溴甲苯 、 calix<4>crown-6 在 sodium hydride 作用下， 以 四氢呋喃 、 N,N-二甲基甲酰胺 为溶剂， 反应 24.25h， 以6%的产率得到43,44-Bis(phenylmethoxy)-3,6,9,12,15,18-hexaoxahexacyclo[18.15.7.126,30.137,41.02,32.019,24]tetratetraconta-1(35),2(32),19(24),20,22,26,28,30(44),33,37(43),38,40-dodecaene
  参考文献：
  名称：

  Calix[4]arene-dithiacrown ethers: synthesis and potentiometric membrane sensing of Hg2+

  摘要：

  A series of calix[4]arene-dithiacrown-5 and -dithiacrown-6 Compounds in cone and 1,3-alternate conformations has been synthesized. Responses of these ionophores to Hg2+ and competing metal ions were determined in solvent polymeric membrane electrodes. High potentiometric selectivity for Hg2+ over Na+ and a variety of transition and heavy metal ions was obtained. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2009.11.058

文献信息

• Calix[4]arene-dithiacrown ethers: synthesis and potentiometric membrane sensing of Hg2+
  作者：Yanfei Yang、Xiaodan Cao、Malgorzata Surowiec、Richard A. Bartsch

  DOI：10.1016/j.tet.2009.11.058

  日期：2010.1

  A series of calix[4]arene-dithiacrown-5 and -dithiacrown-6 Compounds in cone and 1,3-alternate conformations has been synthesized. Responses of these ionophores to Hg2+ and competing metal ions were determined in solvent polymeric membrane electrodes. High potentiometric selectivity for Hg2+ over Na+ and a variety of transition and heavy metal ions was obtained. (C) 2009 Elsevier Ltd. All rights reserved.