[Cu(C6H5C(O)NNC(CH3)C5H4N)(μ1.5-N(CN)2)] | 1001847-42-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: [Cu(C6H5C(O)NNC(CH3)C5H4N)(μ1.5-N(CN)2)]
• CAS: 1001847-42-2
• 化学式: C₂N₃*C₁₄H₁₂N₃O*Cu
• 分子量: 367.857
• InChiKey: OXOGDVMKMGRZFN-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  3.34
• 重原子数：
  24.0
• 可旋转键数：
  3.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  118.1
• 氢给体数：
  0.0
• 氢受体数：
  5.0

反应信息

• 作为产物：
  描述：

  2-acetylpyridine benzoylhydrazone 、 copper(II) perchlorate hexahydrate 、 sodium dicyanamide 以 甲醇 、 水 为溶剂， 以62%的产率得到[Cu(C6H5C(O)NNC(CH3)C5H4N)(μ1.5-N(CN)2)]
  参考文献：
  名称：

  Synthesis, crystal structures and magnetic studies of dicyanamide bridged two new 1D copper(II) complexes

  摘要：

  Two new dicyanamide bridged 1D polynuclear copper(II) complexes [Cu(L-1){mu(1,5)-N(CN)(2)}](n) (1) [(LH)-H-1 = C6H5C(O)NHN=C(CH3)C5H4N] and [Cu(L-2){mu(1,5)-N(CN)(2)}](n) (2) [(LH)-H-2 = C6H5C(O)CHC(CH3)=NCH2CH2N(CH3)(2)] have been synthesised and structures of both the complexes and their crystal packing arrangements have been established by X-ray crystallography. For complex 1, a tridentate hydrazone ligand ((LH)-H-1) obtained by the condensation of benzhydrazide and 2-acetylpyridine is used, whereas a tridentate Schiff base ((LH)-H-2) derived from benzoylacetone and 2-dimethylaminoethylamine is employed for the preparation of complex 2. Variable temperature magnetic susceptibility measurement studies indicate there are weak antiferromagnetic interactions with J values -0.10 and -1.41 cm(-1) for 1 and 2, respectively. (C) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2007.05.034