Stereoelectronic effects in the ring cleavage of methyl glycopyranosides using dimethylboron bromide
作者:Yvan Guindon、Paul C. Anderson
DOI:10.1016/s0040-4039(00)95447-9
日期:1987.1
Treatment of methyl D-glycopyranosides with dimethylboron bromide followed by a nucleophile gives acyclic products resulting from selective cleavage of the ring carbon-oxygen bond. The results are rationalized based on stereoelectronic considerations.