| 36103-28-3

• 分子结构分类: 有机化合物 - 有机氧化合物
• CAS: 36103-28-3
• 化学式: H₂O₂Sr
• 分子量: 123.619
• InChiKey: UUCCCPNEFXQJEL-ZSJDYOACSA-L

反应信息

• 作为产物：
  描述：

  生成
  参考文献：
  名称：

  The crystal structure of Sr(OD)2

  摘要：

  The crystal structure of Sr(OD)(2) has been determined from a Reitveld refinement of time-of-flight neutron diffraction data, and the deuterium atom positions have been determined for the first time. The structure is orthorhombic: Pnma, a = 9.8269(5) Angstrom, b = 3.9051(2) Angstrom, c = 6.0733(3) Angstrom, V = 233.06 Angstrom(3), D-x = 3.466 g cm(-3) R(wp) = 3.9346, R(p) = 2.95%, reduced chi(2) = 4.774 for 81 variables. Although the data were collected at 12 K, the H atoms have large thermal parameters suggesting the possibility of some disorder. Relationships of the structure to the structures of YOOH, SrBr2, SrI2, and SrBr2 . H2O are discussed. (C) 1995 Academic Press, Inc.

  DOI：

  10.1016/0022-4596(95)80023-i

文献信息

• Infrared Spectra of the Group 2 Metal Dihydroxide Molecules
  作者：Lester Andrews、Xuefeng Wang

  DOI：10.1021/ic0483794

  日期：2005.1.1

  Group 2 metal atoms (Mg, Ca, Sr, and Ba) react on ultraviolet photoexcitation with O(2), H(2) mixtures in solid argon at 10 K to produce new absorptions in the O-H and O-M-O stretching regions. The effect of detailed isotopic substitution on these two absorptions identifies the M(OH)(2) molecules. The stepwise decrease in the O-H stretching modes in this chemical family demonstrates an increase in

  第2组金属原子（Mg，Ca，Sr和Ba）在紫外光激发下与固态氩气中的O（2），H（2）混合物在10 K下反应，从而在OH和OMO拉伸区域中产生新的吸收。详细的同位素取代对这两个吸收的影响确定了M（OH）（2）分子。在该化学家族中，OH拉伸模式的逐步降低表明离子特征的增加，这与类似固体化合物的碱强度的增加平行。