1,1,2,2-Tetrafluoro-2-[1,1,1,2,3,3-hexafluoro-3-(1,2,2-trifluoroethenoxy)propan-2-yl]oxyethanesulfonamide | 446312-71-6

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磺酸及其衍生物
• 英文名称: 1,1,2,2-Tetrafluoro-2-[1,1,1,2,3,3-hexafluoro-3-(1,2,2-trifluoroethenoxy)propan-2-yl]oxyethanesulfonamide
• 英文别名: 1,1,2,2-tetrafluoro-2-[1,1,1,2,3,3-hexafluoro-3-(1,2,2-trifluoroethenoxy)propan-2-yl]oxyethanesulfonamide
• CAS: 446312-71-6
• 化学式: C₇H₂F₁₃NO₄S
• 分子量: 443.142
• InChiKey: LEDXOMHMAMUMRK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  26
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  87
• 氢给体数：
  1
• 氢受体数：
  18

反应信息

• 作为反应物：
  描述：

  1,1,2,2-Tetrafluoro-2-[1,1,1,2,3,3-hexafluoro-3-(1,2,2-trifluoroethenoxy)propan-2-yl]oxyethanesulfonamide 、 六甲基二硅氮烷 反应 2.0h， 生成
  参考文献：
  名称：

  EP1359142

  摘要：

  公开号：
• 作为产物：
  描述：

  全氟(4-甲基-3,6-二氧杂-7-辛烯)磺酰氟 在 lithium hexamethyldisilazane 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 反应 2.0h， 以86%的产率得到1,1,2,2-Tetrafluoro-2-[1,1,1,2,3,3-hexafluoro-3-(1,2,2-trifluoroethenoxy)propan-2-yl]oxyethanesulfonamide
  参考文献：
  名称：

  Synthesis of novel perfluorosulfonamide monomers and their application

  摘要：

  The novel perfluorosulfonamide monomers and their preparation methods have been developed. The ternary-copolymer membranes, utilizing the perfluorosulfonamide monomers as the cross-linking site, can be efficiently converted to the cross-linked membranes with the strictly controlled structure. The novel cross-linking method has proved to be effective for the improvement of the mechanical properties at high temperature, while keeping its high proton conductivity. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jfluchem.2006.05.015

文献信息

• Synthesis of novel perfluorosulfonamide monomers and their application
  作者：Nobuyuki Uematsu、Nobuto Hoshi、Takehiro Koga、Masanori Ikeda

  DOI：10.1016/j.jfluchem.2006.05.015

  日期：2006.8

  The novel perfluorosulfonamide monomers and their preparation methods have been developed. The ternary-copolymer membranes, utilizing the perfluorosulfonamide monomers as the cross-linking site, can be efficiently converted to the cross-linked membranes with the strictly controlled structure. The novel cross-linking method has proved to be effective for the improvement of the mechanical properties at high temperature, while keeping its high proton conductivity. (c) 2006 Elsevier B.V. All rights reserved.
• EP1359142
  申请人：——

  公开号：——

  公开（公告）日：——