Cu2(3,5-dimethylpyrazole)2(μ-acetato)4 | 1297291-82-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: Cu2(3,5-dimethylpyrazole)2(μ-acetato)4
• 英文别名: Cu(μ-acetato)4(3,5-dimethylpyrazole)2
• CAS: 1297291-82-7；94351-69-6
• 化学式: C₁₈H₂₈Cu₂N₄O₈
• 分子量: 555.534
• InChiKey: LWAHRJWXRBPAEC-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  3,5-二甲基吡唑 、 copper diacetate 以 水 、 甲苯 为溶剂， 生成 Cu2(3,5-dimethylpyrazole)2(μ-acetato)4
  参考文献：
  名称：

  Effect of the nature of carboxylate anion on the features of intramolecular hydrogen bonding in [Pd(Hdmpz)4](OOCR)2 (R = Me, But, Ph)

  摘要：

  We discovered that reactions of [Pd(OOCMe)(2)] (n) and Pd-3(mu-OOCMe) with 3,5-dimethylpyrazole (Hdmpz) yield mononuclear complex [Pd(Hdmpz)(4)](OOCMe)(2), in which acetate anions can exchange for pivalate or benzoate anions in reactions with proper acids. The specifics of intramolecular hydrogen bonding in the complexes prepared are discussed as dependent on the nature of the carboxylate anion using X-ray crystallography data.

  DOI：

  10.1134/s0036023609090071

文献信息

• Reactions of aqueous copper acetate with triethylamine and 3,5-dimethylpyrazole
  作者：E. V. Perova、M. A. Yakovleva、E. O. Baranova、I. V. Anan’ev、S. E. Nefedov

  DOI：10.1134/s0036023610050104

  日期：2010.5

  The dissolution of aqueous copper acetate in tetrahydrofuran gives the Cu-2(mu-OOCMe)(4)(thf)(2) complex (1), and its reaction with triethylamine in the presence of acetic acid yields "[Cu-2(mu-OOCMe)(4)[mu-OOCMe(HNEt3)]" (n) polymer (2). Complexes 1 and 2 react with 3,5-dimethylpyrazole to form Cu(Hdmpz)(2)(OOCMe)(2) (3) and Cu-2(mu-OOCMe)(4)(Hdmpz)(2) (4), respectively. The structures of complexes 1-4 and that of solvate 4 x 0.5C(6)H(6) (5) are determined by X-ray diffraction.