methacrylic acid-(trans-4-tert-butyl-cyclohexyl ester) | 131809-30-8

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: methacrylic acid-(trans-4-tert-butyl-cyclohexyl ester)
• 英文别名: Methacrylsaeure-(trans-4-tert-butyl-cyclohexylester)；4-(1,1-dimethylethyl)cyclohexyl methacrylate
• CAS: 131809-30-8
• 化学式: C₁₄H₂₄O₂
• 分子量: 224.343
• InChiKey: PILKNUBLAZTESB-HAQNSBGRSA-N

物化性质

• 沸点：
  277.3±9.0 °C(Predicted)
• 密度：
  0.93±0.1 g/cm3(Predicted)

反应信息

• 作为产物：
  描述：

  甲基丙烯酸 、 alkaline earth salt of/the/ methylsulfuric acid 在 正庚烷 、 对甲苯磺酸 作用下， 生成 methacrylic acid-(trans-4-tert-butyl-cyclohexyl ester)
  参考文献：
  名称：

  THE PREPARATION OF SOME ESTERS OF METHACRYLIC ACID

  摘要：

  DOI：

  10.1021/jo01365a013

文献信息

• CURABLE LIQUID/LIQUID/SOLID MULTIPHASIC SUSPENSIONS
  申请人：3M Innovative Properties Company

  公开号：EP4098444A1

  公开（公告）日：2022-12-07

  The present invention relates to curable compositions comprising a plurality of particles, a primary liquid phase comprising at least one polymerizable or cross-linkable organic compound that can form organic polymers or networks, and a secondary liquid phase.

  本发明涉及可固化组合物，该组合物包括多个颗粒、由至少一种可形成有机聚合物或网络的可聚合或可交联有机化合物组成的一级液相以及二级液相。
• Photopolymerizable compositions including a polyurethane methacrylate polymer prepared using a polycarbonate diol, articles, and methods
  申请人：3M INNOVATIVE PROPERTIES COMPANY

  公开号：US11225535B2

  公开（公告）日：2022-01-18

  The present disclosure provides a photopolymerizable composition. The photopolymerizable composition includes a) 40-60 parts by weight of a monofunctional (meth)acrylate monomer, per 100 parts of the total photopolymerizable composition; b) a photoinitiator; and c) a polymerization reaction product of components. A cured homopolymer of the monofunctional (meth)acrylate monomer has a glass transition temperature of 125 degrees Celsius or greater. The polymerization reaction product of components includes i) a diisocyanate; ii) a hydroxy functional methacrylate; iii) a polycarbonate diol; and iv) a catalyst. The polymerization reaction product includes a polyurethane methacrylate polymer. Often, the polycarbonate diol has a number average molecular weight of greater than 1,000 grams per mole (g/mol) or a weighted average of all polycarbonate diols present in the components has a Mn of greater than 1,000 g/mol; alternatively, the polyurethane methacrylate polymer has a weight average molecular weight of 8,000 g/mol or greater. An article is also provided including the photopolymerizable composition reaction product. Further, the present disclosure provides articles and methods of making articles. Methods are additionally provided, including receiving, by a manufacturing device having one or more processors, a digital object comprising data specifying an article; and generating, with the manufacturing device by an additive manufacturing process, the article based on the digital object. A system is also provided, including a display that displays a 3D model of an article; and one or more processors that, in response to the 3D model selected by a user, cause a 3D printer to create a physical object of an article.

  本公开提供了一种可光聚合组合物。这种可光聚合组合物包括 a) 按重量计，每 100 份可光聚合组合物中含 40-60 份单官能团（甲基）丙烯酸酯单体；b) 光引发剂；以及 c) 各组分的聚合反应产物。单官能团（甲基）丙烯酸酯单体的固化均聚物的玻璃化温度为 125 摄氏度或更高。组分的聚合反应产物包括 i) 二异氰酸酯；ii) 羟基官能甲基丙烯酸酯；iii) 聚碳酸酯二元醇；和 iv) 催化剂。聚合反应产物包括聚氨酯甲基丙烯酸酯聚合物。通常，聚碳酸酯二元醇的数均分子量大于 1,000 克/摩尔（g/mol），或存在于组分中的所有聚碳酸酯二元醇的加权平均分子量大于 1,000 克/摩尔；或者，聚氨酯甲基丙烯酸酯聚合物的重量平均分子量大于或等于 8,000 克/摩尔。还提供了一种包括可光聚合组合物反应产物的物品。此外，本公开还提供了物品和制作物品的方法。另外还提供了方法，包括由具有一个或多个处理器的制造设备接收数字对象，该数字对象包括指定物品的数据；以及由制造设备通过增材制造工艺基于数字对象生成物品。还提供了一种系统，包括显示物品三维模型的显示器；以及一个或多个处理器，这些处理器响应用户选择的三维模型，使三维打印机创建物品的物理对象。
• PHOTOPOLYMERIZABLE COMPOSITIONS INCLUDING A POLYURETHANE METHACRYLATE POLYMER PREPARED USING A POLYCARBONATE DIOL, ARTICLES, AND METHODS
  申请人：3M Innovative Properties Company

  公开号：EP3752123A1

  公开（公告）日：2020-12-23
• ORTHODONTIC ARTICLES PREPARED USING A POLYCARBONATE DIOL, AND METHODS OF MAKING SAME
  申请人：3M Innovative Properties Company

  公开号：EP3806774A1

  公开（公告）日：2021-04-21
• ORTHODONTIC ARTICLES PREPARED USING A POLYCARBONATE DIOL, POLYMERIZABLE COMPOSITIONS, AND METHODS OF MAKING THE ARTICLES
  申请人：3M INNOVATIVE PROPERTIES COMPANY

  公开号：US20210171701A1

  公开（公告）日：2021-06-10

  The present disclosure provides an orthodontic article including the reaction product of the polymerizable composition. Further, the present disclosure provides polymerizable compositions and methods of making an orthodontic article. The method includes obtaining a polymerizable composition and selectively curing the polymerizable composition to form an orthodontic article. Further, methods are provided, including receiving, by a manufacturing device having one or more processors, a digital object comprising data specifying an orthodontic article; and generating, with the manufacturing device by an additive manufacturing process, the orthodontic article based on the digital object. A system is also provided, including a display that displays a 3D model of an orthodontic article; and one or more processors that, in response to the 3D model selected by a user, cause a 3D printer to create a physical object of an orthodontic article.