| 1069136-69-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• CAS: 1069136-69-1
• 化学式: C₂₄H₄₄N₂O₁₀
• 分子量: 520.621
• InChiKey: FXXHJRBREACDNS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.0
• 重原子数：
  36.0
• 可旋转键数：
  26.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  144.34
• 氢给体数：
  2.0
• 氢受体数：
  12.0

反应信息

• 作为反应物：
  描述：

  、 在 Methanaminium,N-[(dimethylamino)(3H-1,2,3-triazolo[4,5-b]pyridin-3-yloxy)methylene]-N-methyl-, hexafluorophosphate(1-) 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 25.0h， 以19%的产率得到
  参考文献：
  名称：

  Complexes between hydrogen bonded bisporphyrin tweezers and cholesterol-appended fullerenes as organogelators and liquid crystals

  摘要：

  This paper reports the gelation and liquid crystal properties of a class of new complexes between zinc and copper bisporphyrin and C-60 derivatives. The bisporphyrins are induced by intramolecular hydrogen bonding to adopt a preorganized V-shaped conformation and therefore efficiently complex the C-60 derivatives. As a result, the capacity of their mixtures to gelate alkanes is increased notably. The bisporphyrins themselves and their complexes with the C-60 derivatives form the smectic liquid crystal phase. However, the glassy transition temperature of the complexes decreases considerably. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2009.09.107
• 作为产物：
  描述：

  13,13'-((4,6-dinitro-1,3-phenylene)bis(oxy))bis(2,5,8,11-tetraoxatridecane) 在 palladium 10% on activated carbon 、 氢气 作用下， 以 四氢呋喃 、 甲醇 为溶剂， 反应 22.0h， 生成
  参考文献：
  名称：

  Complexes between hydrogen bonded bisporphyrin tweezers and cholesterol-appended fullerenes as organogelators and liquid crystals

  摘要：

  This paper reports the gelation and liquid crystal properties of a class of new complexes between zinc and copper bisporphyrin and C-60 derivatives. The bisporphyrins are induced by intramolecular hydrogen bonding to adopt a preorganized V-shaped conformation and therefore efficiently complex the C-60 derivatives. As a result, the capacity of their mixtures to gelate alkanes is increased notably. The bisporphyrins themselves and their complexes with the C-60 derivatives form the smectic liquid crystal phase. However, the glassy transition temperature of the complexes decreases considerably. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2009.09.107