1-isopropoxy-3,3,7,7-tetramethyl-2,8,9-trioxa-5-aza-1-germatricyclo[3.3.3.O(1,5)]undecane | 1326705-73-0

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1-isopropoxy-3,3,7,7-tetramethyl-2,8,9-trioxa-5-aza-1-germatricyclo[3.3.3.O(1,5)]undecane
• 英文别名: Ge[(OCH2CH2)N(CH2CMe2O)2](OCH(CH3)2)；Ge[imino-2,2,2',2'-tetramethyl-2,2',2''-triethanol-3H](OCH(CH3)2)
• CAS: 1326705-73-0
• 化学式: C₁₃H₂₇GeNO₄
• 分子量: 333.952
• InChiKey: GKIVGXIQIGJFMS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  bis(2-methyl-2-hydroxypropyl)(2-hydroxyethyl)amine 、 germanium tetra-isopropoxide 以 甲苯 为溶剂， 以81%的产率得到1-isopropoxy-3,3,7,7-tetramethyl-2,8,9-trioxa-5-aza-1-germatricyclo[3.3.3.O(1,5)]undecane
  参考文献：
  名称：

  Synthesis and X-ray diffraction analysis/crystal structure of new germatranes containing methyl substituents in three five-membered chelating rings

  摘要：

  Three monomeric germatranes, 1-isopropoxy-3,3,7,7,10,10-hexamethyl-2,8,9-trioxa-5-aza-1-germatricyclo[3.3.3.0(1.5)]undecane (1), 1-isopropoxy-3,3,7,7-tetramethyl-2,8,9-trioxa-5-aza-1-germatricyclo[3.33.0(1.5)]undecane (2), and 1-isopropoxy-3,3-dimethyl-2,8,9-trioxa-5-aza-1-germatricyclo[3.3.3.0(1.5)]undecane (3) have been synthesized by the reaction of Ge(O-i-Pr)(4) in refluxing toluene with corresponding triethanolamines, (HOCH2CH2)(n)N(CH2CMe2OH)(3-n) (n = 0, L1H(3); n = 1, L2H(3); n = 2, L3H(3)), where the number of CMe2 groups adjacent to a OH functionality varied from 3 (L1H(3)) to 2 (L2H(3)), and to 1 (L3H(3)). These germatranes 1-3 have been characterized by solution H-1 and C-13{H-1) NMR and the solid state structure of 2 has been determined by single crystal X-ray diffraction. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2011.06.013