catena-bis(μ-perchlorato)-{bis(μ-imidazolato)bis(perchlorato)octakis(imidazole)tricopper(II)} | 11127-74-5

• 分子结构分类: 有机化合物 - 有机酸及其衍生物
• 英文名称: catena-bis(μ-perchlorato)-{bis(μ-imidazolato)bis(perchlorato)octakis(imidazole)tricopper(II)}
• 英文别名: [Cu3(imidazole)8(imidazole-1H)2(ClO4)4]n；[Cu3(imH)8(im)2(ClO4)4]n
• CAS: 11127-74-5
• 化学式: 2C₃H₃N₂*8C₃H₄N₂*4ClO₄*3Cu
• 分子量: 1267.21
• InChiKey: HGLQTNQBWYSEQJ-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  copper(II) perchlorate hexahydrate 、 N,N'-羰基二咪唑 以 甲醇 、 水 为溶剂， 以60%的产率得到catena-bis(μ-perchlorato)-{bis(μ-imidazolato)bis(perchlorato)octakis(imidazole)tricopper(II)}
  参考文献：
  名称：

  1D polymeric chain of copper(II) containing imidazolate and perchlorate bridging: Supramolecular synthon involving N–H⋯O hydrogen bonding

  摘要：

  A novel 1D coordination polymer, [Cu-3(imH)8(im)2(ClO4)(4)](n) (1) (imH = imidazole), has been synthesized and X-ray crystallographically characterized. In the long range form 1 affords 3D network through N-H...O hydrogen bonding and displays intraligand (1)(pi-pi*) fluorescence and intraligand (3)(pi-pi*) phosphorescence in glassy solution (DMF at 77 K). (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2005.08.008