3-bromo-4-(2-ethylhexyloxy)thiophene | 1286239-40-4

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 3-bromo-4-(2-ethylhexyloxy)thiophene
• 英文别名: 3-Bromo-4-(2-ethylhexoxy)thiophene；3-bromo-4-(2-ethylhexoxy)thiophene
• CAS: 1286239-40-4
• 化学式: C₁₂H₁₉BrOS
• 分子量: 291.252
• InChiKey: FKRCUZDGCXVSPW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.4
• 重原子数：
  15
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  37.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  在 copper chromite 、 水 、 sodium hydroxide 作用下， 以 喹啉 、 乙醇 为溶剂， 反应 3.05h， 生成 3-bromo-4-(2-ethylhexyloxy)thiophene
  参考文献：
  名称：

  3-Alkoxy-4-bromothiophenes: general synthesis of monomers and regio-selective preparation of two dimers

  摘要：

  3-Alkoxy-4-bromothiophenes were synthesized in three steps from the readily available methyl 2-carboxylate-3-hydroxythiophene and two isomers of bithiophenes based on the 3-bromo-4-methoxythiophene moiety were regio-selectively prepared. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2011.01.050

文献信息

• 3-Alkoxy-4-bromothiophenes: general synthesis of monomers and regio-selective preparation of two dimers
  作者：Gurunathan Savitha、Noémie Hergué、Erwan Guilmet、Magali Allain、Pierre Frère

  DOI：10.1016/j.tetlet.2011.01.050

  日期：2011.3

  3-Alkoxy-4-bromothiophenes were synthesized in three steps from the readily available methyl 2-carboxylate-3-hydroxythiophene and two isomers of bithiophenes based on the 3-bromo-4-methoxythiophene moiety were regio-selectively prepared. (C) 2011 Elsevier Ltd. All rights reserved.