aquabis(indole-2-carboxylato)(1,10-phenanthroline)manganese(II)N,N-dimethylacetamide | 615554-46-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: aquabis(indole-2-carboxylato)(1,10-phenanthroline)manganese(II)N,N-dimethylacetamide
• CAS: 615554-46-6
• 化学式: C₄H₉NO*C₃₀H₂₂MnN₄O₅
• 分子量: 660.588
• InChiKey: BJGMKLVJXDBVMR-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  吲哚-2-羧酸 以 N,N-二甲基乙酰胺 、 水 为溶剂， 生成 aquabis(indole-2-carboxylato)(1,10-phenanthroline)manganese(II)N,N-dimethylacetamide
  参考文献：
  名称：

  Synthesis, crystal structure and IR spectroscopy of MnII(2-IC)2(NC)(DMSO) and [MnII(2-IC)2(phen)(H2O)]·DMA; (2-HIC, indole-2-carboxylic acid; phen, 1,10-phenanthroline; NC, 2,9-dimethyl-1,10-phenanthroline; DMSO, dimethyl sulfoxide; DMA, dimethyl acetamide); catalysts for the disproportionation of hydrogen peroxide

  摘要：

  Two ternary complexes of manganese(II) indole-2-carboxylate (2-IC) with 2,9-dimethyl-1,10-phenanthroline (NC) and 1,10-phenanthroline (phen) in dimethyl sulfoxide (DMSO) or dimethylacetamide (DMA) were synthesized, their X-ray crystal structure and IR spectroscopy characteristics were determined. In compound Mn-II(2-IC)(2)(NC)(DMSO) (1), Mn(II) is six-coordinate by one bidentate NC ligand and two bidentate 2-IC anionic ligands. The crystal structure has revealed a seven-coordinate Mn(II) when a moderately long contact distance Mn-O (DMSO 2.643(2) Angstrom) is included in the coordination list: the Mn(II) configuration can be described as a distorted capped octahedron. Individual molecules are linked into chains running parallel to the a axis by intermolecular hydrogen bonding. In compound Mn-II(2-IC)(phen)(H2O)] . DMA (2), the manganese atom is six-coordinate by one bidentate phen ligand and two 2-IC anionic ligands one of which is monodentate, and the other is bidentate. The coordination sphere is completed by one water molecule, the Mn(II) environment can be described as a very distorted octahedron. The individual molecules are associated in dimmer structure by intermolecular hydrogen bonding. The crystal structure of 2 is completed by a disordered DMA solvate molecule. These two complexes are catalysts for the disproportionation of H2O2 in the presence of added imidazole. (C) 2003 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(03)00126-8