mercury(II) 7-carboxyheptane-1,3-bis(thiolate) | 142202-17-3

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: mercury(II) 7-carboxyheptane-1,3-bis(thiolate)
• CAS: 142202-17-3
• 化学式: C₈H₁₄O₂S₂*Hg
• 分子量: 406.92
• InChiKey: CFALCOUSKWDYJF-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  1.48
• 重原子数：
  13.0
• 可旋转键数：
  7.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.88
• 拓扑面积：
  37.3
• 氢给体数：
  1.0
• 氢受体数：
  3.0

反应信息

• 作为产物：
  描述：

  (+/-)-二氢硫辛酸 、 mercury dichloride 以 N,N-二甲基甲酰胺 为溶剂， 生成 mercury(II) 7-carboxyheptane-1,3-bis(thiolate)
  参考文献：
  名称：

  Synthesis and characterization of metal derivatives of dihydrolipoic acid and dihydrolipoamide

  摘要：

  Complexes formed by the dianions LH2- and L'2- deriving from dihydrolipoic acid (LH3) and dihydrolipoamide (L'H2), respectively, by substitution of the hydrogen atoms of the thiol groups with Ni(II), Co(II), Hg(II) and Cu(I) ions were synthesized, isolated and characterized. In all these compounds the metal ions are coordinated to the thiolic sulfur atoms of the ligands. Potentiometric and spectroscopic data (IR, UV-Vis, EPR and XPS) obtained for these complexes or for their solutions are discussed.

  DOI：

  10.1016/s0020-1693(00)80765-3