N-hexadecylpyrrole-2-carbaldehyde | 1017684-18-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: N-hexadecylpyrrole-2-carbaldehyde
• 英文别名: 1-hexadecyl-1H-pyrrole-2-carbaldehyde；N-hexadecylpyrrole-2-carboxaldehyde；1-hexadecylpyrrole-2-carbaldehyde
• CAS: 1017684-18-2
• 化学式: C₂₁H₃₇NO
• 分子量: 319.531
• InChiKey: MIZOECPPEWCNKO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.1
• 重原子数：
  23
• 可旋转键数：
  16
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.76
• 拓扑面积：
  22
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  N-hexadecylpyrrole-2-carbaldehyde 、 在 sodium hydride 作用下， 生成
  参考文献：
  名称：

  Synthesis and properties of novel low band-gap polymers bearing squaraine units

  摘要：

  Novel main-chain-conjugated poly(carbazol-alt-squaraine) and poly (dipyridyl-alt-squaraine) were successfully synthesized through direct polycondensation of 9-(2-ethylhexyl)carbazole-bridged or dipyridyl-bridged bispyrrole and squaric acid. The structures and properties of the polymers were characterized using (1)H NMR, FT-IR, UV-vis and cyclic voltammetry. Both polymers exhibit excellent solubility in common organic solvents and good thermal stability. Their UV-vis absorption spectra indicated the polymers have broad and strong spectral responses from 200 nm to 900 nm, which reveals a low optical band gap around 1.38 eV, suggesting that they may be promising candidates for organic solar cells. (C) 2009 Ying Li. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.

  DOI：

  10.1016/j.cclet.2009.09.003

文献信息

• Synthesis and properties of two novel copolymers based on squaraine and fluorene units for solar cell materials
  作者：Zheng Wang、Wei Zhang、Feng Tao、Kai Ge Meng、Long Yi Xi、Ying Li、Qing Jiang

  DOI：10.1016/j.cclet.2010.12.052

  日期：2011.8

  Two novel copolymers based on squaraine and fluorine units have been synthesized through palladium catalyzed Suzuki coupling reaction and Sonogashira coupling reaction, respectively. The structures and properties of the two copolymers were characterized by FT-IR, NMR, UV-vis absorbance (Abs), gel permeation chromatography (GPC), thermal gravimetric analysis (TGA), differential scanning calorimetry (DSC) and cyclic voltammetry (CV). The solution absorption spectrums of P-1 and P-2 show two distinct absorption bands, one locates at 300-500 nm and the other at 600-800 nm. The absorption spectrums of P-1 and P-2 in films are broadened obviously and the spectral responses are extended up to 900 nm. Thermal gravimetric analysis demonstrates that the polymers are stable. Cyclic voltammetry experiment shows that the band gaps of the copolymers are 1.65 eV and 1.67 eV, respectively, suggesting their potential for applications as solar cells materials. (C) 2011 Ying Li. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.
• Synthesis and properties of novel low band-gap polymers bearing squaraine units
  作者：Wei Zhang、Zheng Wang、Yu Sheng Tang、Zhi Gang Xu、Ying Li、Qing Jiang

  DOI：10.1016/j.cclet.2009.09.003

  日期：2010.2

  Novel main-chain-conjugated poly(carbazol-alt-squaraine) and poly (dipyridyl-alt-squaraine) were successfully synthesized through direct polycondensation of 9-(2-ethylhexyl)carbazole-bridged or dipyridyl-bridged bispyrrole and squaric acid. The structures and properties of the polymers were characterized using (1)H NMR, FT-IR, UV-vis and cyclic voltammetry. Both polymers exhibit excellent solubility in common organic solvents and good thermal stability. Their UV-vis absorption spectra indicated the polymers have broad and strong spectral responses from 200 nm to 900 nm, which reveals a low optical band gap around 1.38 eV, suggesting that they may be promising candidates for organic solar cells. (C) 2009 Ying Li. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.