| 262611-43-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• CAS: 262611-43-8
• 化学式: C₂₄H₄₆CoN₈O₁₀
• 分子量: 665.67
• InChiKey: KICAGGDWSHPYAC-LAGLFLAWSA-L

反应信息

• 作为产物：
  描述：

  cobalt(II) chloride hexahydrate 、 (Z,Z)-1,2-dihydroxyimino-3,6-diamino-8,9-O,O-cyclopentylidenenonane-8,9-diol 在 triethylamine 作用下， 以 乙醇 为溶剂， 以72%的产率得到
  参考文献：
  名称：

  Synthesis of (Z,Z)-1, 2-dihydroxyimino-3, 6-diamlno-8, 9-O,O-cyclopentylidenenonane-8, 9-diol and Its Complexes with Copper(II), Nickel(II), Cobalt(II) and Uranyl(VI)

  摘要：

  The new vic-dioxime ligand,(Z,Z)-1,2-dihydroxyimino-3,6-diamino-8,9-O,O-cylopentylidenenonane-8,9-diol (LH2) was synthesized by treating 1,3-diamino-5,6-O,O-cylopentylidenehexane-5,6-diol (R-NH2) with anti-chloroglyoxime in the presence of a base, e.g. triethylamine. vic-Dioximes have been found to be in the Z,Z-form according to H-1 NMR and C-13 NMR data. Mononuclear complexes having a metal-ligand ratio of 1:2 have been prepared with Co(II), Cu(II) and Ni(II) salts. However, the metal-ligand ratio and structure of the UO2(VI) complex was found to be 1:1 and dinuclear. The ligand and its complexes were characterized by magnetic susseptibility, elemental analyses, IR, UV-Vis., H-1 NMR,C-13 NMR, TGA and DTA studies. Structures for the complexes are suggested.

  DOI：

  10.1080/00945710009351757