4-[4-[3,5-Bis[4-(3-carboxypropanoylamino)phenyl]phenyl]anilino]-4-oxobutanoic acid | 1245133-30-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-[4-[3,5-Bis[4-(3-carboxypropanoylamino)phenyl]phenyl]anilino]-4-oxobutanoic acid
• 英文别名: 4-[4-[3,5-bis[4-(3-carboxypropanoylamino)phenyl]phenyl]anilino]-4-oxobutanoic acid
• CAS: 1245133-30-5
• 化学式: C₃₆H₃₃N₃O₉
• 分子量: 651.673
• InChiKey: OQQOCAGBYMYFOR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  48
• 可旋转键数：
  15
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  199
• 氢给体数：
  6
• 氢受体数：
  9

反应信息

• 作为反应物：
  描述：

  、 4-[4-[3,5-Bis[4-(3-carboxypropanoylamino)phenyl]phenyl]anilino]-4-oxobutanoic acid 以 四氢呋喃 为溶剂， 生成
  参考文献：
  名称：

  A potent triphenylbenzene-based H-bonding donor to assist formation of two-component organogels with stilbazoles

  摘要：

  Two-component organogelators based on a discotic H-bonding donor of 1,3,5-tris(4-amidobutanoic acid)phenyl benzene (2), and acceptors of 4-(4-alkoxybenzoyloxy)-4'-stilbazole derivatives were reported. These complexes showed good gelation ability for alcohols, which are known to be unfavorable for H-bonding formation. SEM study revealed that sheet-like network, nanotapes, and nanorods were gained from the self-assembling of the complexes with small difference of the carbon chain length. Based on XRD, IR, temperature-dependent H-1 NMR, and UV-vis absorption investigations, the gel-phase materials were generated from 1D columnar-type packing of complexes facilitated by cooperative H-bonding, it-stacking, and van der Walls interactions. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2010.05.043
• 作为产物：
  描述：

  丁二酸酐 、 1,3,5-三(4-氨苯基)苯 以 四氢呋喃 为溶剂， 反应 24.0h， 以84%的产率得到4-[4-[3,5-Bis[4-(3-carboxypropanoylamino)phenyl]phenyl]anilino]-4-oxobutanoic acid
  参考文献：
  名称：

  A potent triphenylbenzene-based H-bonding donor to assist formation of two-component organogels with stilbazoles

  摘要：

  Two-component organogelators based on a discotic H-bonding donor of 1,3,5-tris(4-amidobutanoic acid)phenyl benzene (2), and acceptors of 4-(4-alkoxybenzoyloxy)-4'-stilbazole derivatives were reported. These complexes showed good gelation ability for alcohols, which are known to be unfavorable for H-bonding formation. SEM study revealed that sheet-like network, nanotapes, and nanorods were gained from the self-assembling of the complexes with small difference of the carbon chain length. Based on XRD, IR, temperature-dependent H-1 NMR, and UV-vis absorption investigations, the gel-phase materials were generated from 1D columnar-type packing of complexes facilitated by cooperative H-bonding, it-stacking, and van der Walls interactions. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2010.05.043

文献信息

• A potent triphenylbenzene-based H-bonding donor to assist formation of two-component organogels with stilbazoles
  作者：Oudjaniyobi Simalou、Pengchong Xue、Ran Lu

  DOI：10.1016/j.tetlet.2010.05.043

  日期：2010.7

  Two-component organogelators based on a discotic H-bonding donor of 1,3,5-tris(4-amidobutanoic acid)phenyl benzene (2), and acceptors of 4-(4-alkoxybenzoyloxy)-4'-stilbazole derivatives were reported. These complexes showed good gelation ability for alcohols, which are known to be unfavorable for H-bonding formation. SEM study revealed that sheet-like network, nanotapes, and nanorods were gained from the self-assembling of the complexes with small difference of the carbon chain length. Based on XRD, IR, temperature-dependent H-1 NMR, and UV-vis absorption investigations, the gel-phase materials were generated from 1D columnar-type packing of complexes facilitated by cooperative H-bonding, it-stacking, and van der Walls interactions. (C) 2010 Elsevier Ltd. All rights reserved.