(3S)-3-[(2S)-2-methyl-3-oxobutyl]oxolan-2-one | 1228187-26-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 内酯类
• 英文名称: (3S)-3-[(2S)-2-methyl-3-oxobutyl]oxolan-2-one
• CAS: 1228187-26-5
• 化学式: C₉H₁₄O₃
• 分子量: 170.208
• InChiKey: IBSYDXNDQOJSLK-POYBYMJQSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.8
• 重原子数：
  12
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.78
• 拓扑面积：
  43.4
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  (3S)-3-[(2S)-3-hydroxy-2-methylbutyl]oxolan-2-one 在 戴斯-马丁氧化剂 作用下， 以 二氯甲烷 为溶剂， 生成 (3S)-3-[(2S)-2-methyl-3-oxobutyl]oxolan-2-one
  参考文献：
  名称：

  Synthesis of a proposed structure for the diffusible extracellular factor of Xanthomonas campestris pv. campestris

  摘要：

  A proposed structure for the diffusible extracellular factor (DF) of Xanthomonas campestris pv. campestris (Xcc) has been synthesized. Its MS spectrum and biological activity, however, contradict those of the natural product previously reported, suggesting that the structure for DF of Xcc must be reexamined. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2010.02.088

文献信息

• Synthesis of a proposed structure for the diffusible extracellular factor of Xanthomonas campestris pv. campestris
  作者：Arata Yajima、Nagisa Imai、Alan R. Poplawsky、Tomoo Nukada、Goro Yabuta

  DOI：10.1016/j.tetlet.2010.02.088

  日期：2010.4

  A proposed structure for the diffusible extracellular factor (DF) of Xanthomonas campestris pv. campestris (Xcc) has been synthesized. Its MS spectrum and biological activity, however, contradict those of the natural product previously reported, suggesting that the structure for DF of Xcc must be reexamined. (C) 2010 Elsevier Ltd. All rights reserved.