diethyltritiumgermane | 1287701-34-1

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机氧化物
• 英文名称: diethyltritiumgermane
• 英文别名: Et2GeT(+)
• CAS: 1287701-34-1
• 化学式: C₄H₁₁Ge
• 分子量: 133.713
• InChiKey: NCNWNHSMPBRADY-XHHURNKPSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.3
• 重原子数：
  5.0
• 可旋转键数：
  2.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  二丁醚 、 diethyltritiumgermane 以 neat (no solvent, gas phase) 为溶剂， 生成 butoxydimethylgermane-t 、 butoxydiethylgermane-t
  参考文献：
  名称：

  Radiochemical study of gas-phase reactions of nucleogenic diethylgermyl cations with dibutyl ether and 1-butanol

  摘要：

  Reactions of tritium-labeled free diethylgermyl cations with dibutyl ether and 1-butanol in a gas phase were studied by the radiochemical method. Mechanisms of the corresponding ion-molecular reactions were suggested, and the most probable paths of the cation (C2H5)(2)TGe+ conversion into other isomeric forms were shown.

  DOI：

  10.1134/s1070363211070164

文献信息

• Radiochemical investigation of the interaction of nucleogenic diethylgermylium ions with methyl tert-butyl ether
  作者：D. L. Myalochkin、T. A. Kochina、D. V. Vrazhnov、V. V. Avrorin、E. N. Sinotova

  DOI：10.1134/s1070363210110095

  日期：2010.11

  Radiochemical method was used in the study of the interaction of free diethylgermylium cations with methyl tert-butyl ether in the gas and condensed phases, and the mechanisms of the relevant ion-molecular reactions were proposed. The most probable pathways of the (C2H5)(2)TGe+ cation transformation into other isomeric forms are shown as a result of B3LYP calculation with cc-pVTZ basis set.