3-hydroxy-5-methoxy-4,6-dimethyl-2-pyridyl n-octyl telluride | 1062541-59-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 3-hydroxy-5-methoxy-4,6-dimethyl-2-pyridyl n-octyl telluride
• 英文别名: 5-Methoxy-4,6-dimethyl-2-octyltellanylpyridin-3-ol
• CAS: 1062541-59-6
• 化学式: C₁₆H₂₇NO₂Te
• 分子量: 392.996
• InChiKey: KREQGKDWQVMVDD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.52
• 重原子数：
  20
• 可旋转键数：
  9
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.69
• 拓扑面积：
  42.4
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  1-溴辛烷 、 在 sodium tetrahydroborate 作用下， 以 乙醇 为溶剂， 反应 1.0h， 生成 3-hydroxy-5-methoxy-4,6-dimethyl-2-pyridyl n-octyl telluride
  参考文献：
  名称：

  Catalytic Chain-Breaking Pyridinol Antioxidants

  摘要：

  When assayed for their capacity to inhibit azo-initiated peroxidation of linoleic acid in a water/chlorobenzene two-phase system, tellurium-containing 3-pyridinols were readily regenerable by N-acetylcysteine contained in the aqueous phase. The best inhibitors quenched peroxyl radicals more efficiently than alpha-tocopherol, and the duration of inhibition was limited only by the availability of the thiol reducing agent. The compounds were also found to catalyze reduction of hydrogen peroxide in the presence of thiol reducing agent.

  DOI：

  10.1021/ol801983n