| 244071-99-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• CAS: 244071-99-6
• 化学式: C₄₀H₃₄N₂O₂P₂Pt
• 分子量: 831.75
• InChiKey: FRXMRPNAOLNMGT-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  carbanide;1-[2-(diphenylphosphanylamino)phenyl]ethanone;platinum(2+) 以 xylene 为溶剂， 以64%的产率得到
  参考文献：
  名称：

  Orthometalation of Functionalized Phosphinoamines with Late Transition Metal Complexes

  摘要：

  The neutral metal complexes cis-[Pt(CH3)(2)-{o-Ph2PN(H)C6H4C(O)CH3-P}(2)] and [RhCl2(Cp*){o-Ph-2-PN(H)C6H4C(O)Ph-P}] are excellent precursors for new five-membered M-P-N-C-C metallacycles via sigma(C-sp(2)-H) bond activation. The synthesis and characterization including the molecular structures of cis-[Pt{o-Ph2PN(H)C6H3C(O)CH3-P,C}(2)]. OEt2 and [RhCl(Cp*) {o-Ph2PN(H)C6H3C(O)Ph-P,C}]. 0.5CHCl(3) are reported.

  DOI：

  10.1021/om990363b