bis(2-[(phenylethylimino)ethyl]phenoxy)iodo cobalt(III) | 1206903-70-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: bis(2-[(phenylethylimino)ethyl]phenoxy)iodo cobalt(III)
• CAS: 1206903-70-9
• 化学式: C₃₂H₃₂CoIN₂O₂
• 分子量: 662.516
• InChiKey: HNVUVGWGUZAASH-BMBSNIPDSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• sp3杂化的碳原子比例：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  bis(2-[(phenylethylimino)ethyl]phenoxy)cobalt(II) 、 碘 以 二氯甲烷 为溶剂， 生成 bis(2-[(phenylethylimino)ethyl]phenoxy)iodo cobalt(III)
  参考文献：
  名称：

  Efficient coupling of CO2 and epoxides with bis(phenoxyiminato) cobalt(III)/Lewis base catalysts

  摘要：

  A series of unbridged bis(phenoxyiminato) cobalt(III)complexes were synthesized and studied as catalysts for the coupling of CO2 and epoxide. Dimethylamino pyridine (DMAP) and tetrabutyl ammonium bromide (Bu4NBr). were used as co-catalysts in the reaction. Both Co(III)/DMAP and Co(III)/Bu4NBr systems showed high catalytic activity and selectivity in the Coupling of n-hexyl oxide and CO2, resulting in n-hexyl carbonate. Several mono- and di-substituted terminal epoxides were also tested. The reaction mechanism of the Co(III)/DMAP system was investigated in detail using ESI-MS revealing that in addition to the main product, cyclic carbonate, traces of oligomers are formed. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2009.07.009