Fe(salmeten)Cl | 1196736-84-1

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: Fe(salmeten)Cl
• 英文别名: Fe(III)(Cl)(bis(salicylideneaminopropyl)methylamine)；iron(3+);2-[3-[methyl-[3-[(2-oxidophenyl)methylideneamino]propyl]amino]propyliminomethyl]phenolate;chloride
• CAS: 1196736-84-1
• 化学式: C₂₁H₂₅ClFeN₃O₂
• 分子量: 442.748
• InChiKey: JCXGIKKHWPSVPP-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  -0.91
• 重原子数：
  28
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  74.1
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  Fe(salmeten)Cl 以 甲醇 、 氯仿 为溶剂， 生成
  参考文献：
  名称：

  Synthesis and characterization of imidazolate-bridged iron(III)–copper(II) and manganese(III)–copper(II) binuclear complexes

  摘要：

  DOI：

  10.1039/dt9890000943
• 作为产物：
  描述：

  iron(III) chloride hexahydrate 、 2-([[3-(3-methyl[3-[(2-hydrobenzylidene)amino]propyl]amino)propyl]imino]methyl)phenol 在 triethylamine 作用下， 以 乙醇 为溶剂， 以60%的产率得到Fe(salmeten)Cl
  参考文献：
  名称：

  A Mixed-Valence Mixed-Spin Prussian-Blue-Like Heptanuclear Complex

  摘要：

  DOI：

  10.1002/1521-3773(20000818)39:16<2885::aid-anie2885>3.0.co;2-4

文献信息

• Spin crossover in heterodinuclear iron(III) Schiff-base complexes
  作者：Cynthia T. Brewer、Greg Brewer、Leopold May、Jennifer Sitar、Ru Wang

  DOI：10.1039/dt9930000151

  日期：——

  The reaction of a nickel(II) imidazolate complex [NiL1](H2L1= 5-o-[5-chloro-2-hydroxyphenyl)phenylmethyleneamino]phenyliminomethyl}imidazole) with iron(III) Schiff-base complexes [FeL2Cl], [FeL3]+ and [FeL4]+[H2L = R(NCHC6H4OH-o)2; R =(CH2)2(L1), (CH2)3NH(CH2)3(L2) or (CH2)3NMe(CH2)3(L3)] yielded the imidazolate-bridged heterodinuclear complexes [FeL2(NiL1)Cl], [FeL3(NiL1)]BPh4 and [FeL4(NiL1)]BPh4

  咪唑镍（II）配合物[NiL 1 ]（H 2 L 1 = 5- o- [5-氯-2-羟基苯基）苯基亚甲基氨基]苯基亚氨基甲基}咪唑）与铁（III）席夫碱配合物的反应[ FeL 2 Cl]，[FeL 3 ] +和[FeL 4 ] + [H 2 L = R（N CHC 6 H 4 OH- o）2；R =（CH 2）2（L 1），（CH 2）3 NH（CH 2）3（L 2）或（CH 2） 3 NMe（CH 2） 3（L 3）]生成咪唑基桥联的异双核络合物[FeL 2（NiL 1）Cl]，[FeL 3（NiL 1）] BPh 4和[FeL 4（NiL 1）] BPh 4，具有可变温度磁化率，Mössbauer和ESR光谱学的特征。它们的光谱和磁性与铁（ III）原子的高自旋/低自旋交叉行为一致。两种类似的铜（ II）配合物[FeL还制备了3（CuL 1）] BPh 4和[FeL 4（CuL 1）]
• Synthesis and Structures of Fe ^III Complexes Bridged by Cyanorhenium Clusters
  作者：Seon‐Mi Park、Youngmee Kim、Sung‐Jin Kim

  DOI：10.1002/ejic.200300255

  日期：2003.11

  bis(3-salicylideneaminopropyl)methylamine] with the Re6 clusters [Re6Q8(CN)6]4− (Q = Se, Te) led to the formation of the nanomolecular (≈2.5 nm) compounds [(CN)2Re6Se8(CN)Fe(L1)}4]·7H2O (1) and [(CN)2Re6Te8(CN)Fe(L2)}4]·4CH3CN·4H2O (2). Both compounds were characterized by single-crystal X-ray diffraction analysis. Compound 1 crystallizes in the triclinic space group P with a = 12.2822(10), b = 14

  FeCl(L1) 和 FeCl(L2) [L1 = bis(3-salicylideneaminopropyl) amine, L2 = bis(3-salicylideneaminopropyl)methylamine] 与 Re6 簇 [Re6Q8(CN)6]4− (Q = Se) 的反应, Te) 导致形成纳米分子 (≈2.5 nm) 化合物 [(CN)2Re6Se8(CN)Fe(L1)}4]·7H2O (1) 和 [(CN)2Re6Te8(CN)Fe(L2) )}4]·4CH3CN·4H2O (2)。两种化合物均通过单晶 X 射线衍射分析表征。化合物 1 在三斜空间群 P 中结晶，a = 12.2822(10), b = 14.2524(10), c = 15.8474(10) A, α = 106.093(10)°, β = 101.992(10)°, γ = 92.438(10)°，Z
• One-step and two-step spin crossover binuclear iron(III) complexes bridged by 4,4′-bipyridine
  作者：Takeshi Fujinami、Koshiro Nishi、Ryoko Kitashima、Keishiro Murakami、Naohide Matsumoto、Seiichiro Iijima、Koshiro Toriumi

  DOI：10.1016/j.ica.2011.06.004

  日期：2011.10

  Two binuclear iron(III) complexes, [(LFeIII)-Fe-1(bpy)(FeL1)-L-III](BPh4)(2) (1) and [(LFeIII)-Fe-2(bpy)(FeL2)-L-III](BPh4)(2) (2), were synthesized and characterized, where H2L1 and H2L2 denote bis(salicylicdeneaminopropyl)methylamine and bis(3-methoxysalicylideneaminopropyl)methylamine, respectively, and bpy denotes 4,4'-bipyridine and BPh4 - denotes tetraphenylborate. Complexes 1 and 2 consist of one and two crystallographically unique Fe sites, respectively, while they have a similar binuclear complex-cation [(LFeIII)-Fe-n(bpy)(FeLn)-L-III](2+) (n = 1, 2) bridged by 4,4'-bipyridine and two tetraphenylborate ions as the counter anions. The magnetic susceptibility measurements of 1 and 2 showed one-step and two-step spin crossover (SCO), respectively. The four saturated six-membered chelate rings at the aminopropyl moieties of 1 exhibit disorder throughout one-step SCO. The two chelate rings of one Fe site of 2 exhibit disorder but the other two of another Fe site do not. The different SCO behaviors of 1 and 2 were ascribed to one and two crystallographically unique Fe sites and the order/disorder at the saturated six-membered chelate rings of aminopropyl moieties. (C) 2011 Elsevier B.V. All rights reserved.
• A Prussian Blue Nanomolecule: Crystal Structure and Low-Temperature Magnetism
  作者：G. Rogez、S. Parsons、C. Paulsen、V. Villar、T. Mallah

  DOI：10.1021/ic015528z

  日期：2001.7.1

  The single-crystal structure of a mixed-valence heptanuclear cyanide-bridged complex Fe(II)Fe(III)6 that may be considered as a model of Prussian blue has been determined. The low-temperature magnetic properties (T < 2 K) reveal a metamagnetic behavior below 220 mK. This is the result of the intermolecular antiferromagnetic interaction between the ferromagnetically coupled high-spin clusters.