[(2S,3R,4R,5S,6R)-4-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-6-(tert-butyl-dimethyl-silanyloxymethyl)-5-methyl-tetrahydro-pyran-2-yl]-acetic acid methyl ester | 224629-15-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: [(2S,3R,4R,5S,6R)-4-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-6-(tert-butyl-dimethyl-silanyloxymethyl)-5-methyl-tetrahydro-pyran-2-yl]-acetic acid methyl ester
• CAS: 224629-15-6
• 化学式: C₂₉H₅₂O₆Si₂
• 分子量: 552.899
• InChiKey: UKQJALXYIITVHZ-LQPWPTNLSA-N

物化性质

• 沸点：
  524.9±50.0 °C(predicted)
• 密度：
  1.00±0.1 g/cm3(Temp: 20 °C; Press: 760 Torr)(predicted)

反应信息

• 作为反应物：
  描述：

  [(2S,3R,4R,5S,6R)-4-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-6-(tert-butyl-dimethyl-silanyloxymethyl)-5-methyl-tetrahydro-pyran-2-yl]-acetic acid methyl ester 在 二异丁基氢化铝 作用下， 以 二氯甲烷 为溶剂， 反应 0.33h， 生成 [(2S,3R,4R,5S,6R)-4-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-6-(tert-butyl-dimethyl-silanyloxymethyl)-5-methyl-tetrahydro-pyran-2-yl]-acetaldehyde
  参考文献：
  名称：

  A second generation pyranose-based approach to the F ring (C38–C45) of altohyrtin A

  摘要：

  A second generation approach to the F ring, fragment C38-C45, of altohyrtin A (1) is described herein. The C43-C44 C-glycosidic linkage was prepared and subsequently functionalised with a thioketal moiety. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0957-4166(99)00011-7
• 作为产物：
  描述：

  叔丁基二甲硅基三氟甲磺酸酯 、 ((3R,4R,5S,6R)-4-Benzyloxy-3-hydroxy-6-hydroxymethyl-5-methyl-tetrahydro-pyran-2-yl)-acetic acid methyl ester 以 二氯甲烷 为溶剂， 反应 5.0h， 生成 [(2S,3R,4R,5S,6R)-4-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-6-(tert-butyl-dimethyl-silanyloxymethyl)-5-methyl-tetrahydro-pyran-2-yl]-acetic acid methyl ester
  参考文献：
  名称：

  A second generation pyranose-based approach to the F ring (C38–C45) of altohyrtin A

  摘要：

  A second generation approach to the F ring, fragment C38-C45, of altohyrtin A (1) is described herein. The C43-C44 C-glycosidic linkage was prepared and subsequently functionalised with a thioketal moiety. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0957-4166(99)00011-7