(N,N'-dimethylethylenediamine)(1,1-cyclobutate dicarboxylate)palladium(II) complex | 339149-96-1

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (N,N'-dimethylethylenediamine)(1,1-cyclobutate dicarboxylate)palladium(II) complex
• CAS: 339149-96-1
• 化学式: C₁₀H₁₈N₂O₄Pd
• 分子量: 336.684
• InChiKey: LGSYELJPPDHXHP-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  cis-dichloro-(N,N'-dimethylethylenediamine)palladium(II) complex 、 1,1-环丁基二甲酸 在 AgNO₃ 作用下， 以 乙醇 、 水 为溶剂， 以60%的产率得到(N,N'-dimethylethylenediamine)(1,1-cyclobutate dicarboxylate)palladium(II) complex
  参考文献：
  名称：

  Complex formation reactions of (N,N′-dimethylethylenediamine) palladium(II) with various biologically relevant ligands

  摘要：

  cis-Dichloro-(N,N'-dimethylethylenediamine)palladium(II) [Pd(Me(2)en)Cl-2] was synthesized and characterized. Stoichiometry and stability constants of the complexes formed between [Pd(Me(2)en)(H2O)(2)](2+) with various biologically relevant ligands are investigated. The ligands used are dicarboxylic acids, amino acids, peptides and DNA unit constituents. The results showed the formation of 1:1 complexes with amino acids and dicarboxylic acids. Peptides forms both I:1 complexes and the corresponding deprotonated amide species. DNA constituents form both 1:1 and 1:2 complexes. The concentration distribution of the complexes in solution was evaluated. [Pd(Me(2)en)Cl-2] and [Pd(Me(2)en)(CBDCA)] were isolated and characterized by elemental analysis, FTIR, H-1 NMR, mass spectra and thermal analysis (TGA). (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0277-5387(00)00612-4